solutions were studied by X-ray diffraction, diffuse reflectance UVevisible spectroscopy and field emission scanning electron microscopy. From the characterizations, it was confirmed that Sn can form solid solution with Cd 0.1 Zn 0.9 S and the high crystallinity can be maintained as well. Among all samples, the highest photocatalytic activity was observed on Cd 0.1 Sn 0.01 Zn 0.88 S photocatalyst, with average rate of hydrogen production 3.52 mmol/h, which was ca. 1.5 times higher than the Cd 0.1 Zn 0.9 S photocatalyst. In addition to the high activity, the Cd 0.1 Sn 0.01 Zn 0.88 S also showed high stability at long irradiation time. The role of Sn in preventing electron-hole recombination and photocorrosion was proposed.
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