Three samples taken from two paintings partly burned by fire are investigated for cleaning with lasers. The paintings belong to the collection of the National Gallery of Athens and were made by the great Greek artist Konstantinos Parthenis. To remove the damaged surface and achieve an acceptable restoration result, the optimum combination of fluence and wavelength are sought. Seven different wavelengths with a set of fluences where used, i.e., the five harmonics of a Nd:YAG laser (1064, 532, 355, 266, and 213 nm), a TEA 10.6 µm CO 2 and a free running laser Er:YAG 2.94 µm. Characterization was performed prior and after the cleaning process by optical and electron microscopy and analysis (SEM/BSE EDS), as well as X-Ray Diffraction (XRD). The results of this work indicate that the wavelength in the visible spectrum (532 nm) with fluences between 0.1-0.4J/cm 2 show the optimum cleaning. The optical microscopy observation shows that with these laser parameters the burnt layer was preferentially removed, exposing the original colors that Parthenis had used in these paintings. Electron microscopy imaging and chemical analysis revealed that the original texture and materials of these samples are preserved after irradiation. Since the damage varies along the surface of the painting, more experiments should be performed in order to find and optimize the full cleaning and characterization process for the homogeneous cleaning of the whole surface of the painting.Laser, burnt painting, SEM-EDS, XRD
Laser-based techniques are used more and more frequently for the cleaning of artifacts. Due to the different behavior of each material, when it is irradiated, studies and experiments are performed in order to find the optimum laser parameters for each case. In this work, the laser cleaning of coins is examined. Coins are studied with analytical methods in order to detect the corrosion products and the accretions. This information along with the composition of the coins' alloys is fed into an in-house developed program which estimates the penetration depth of the laser beam as well as the laser fluence for which the alloy starts to melt. Exploiting this information, laser cleaning of coins is performed with various conditions and parameters. Finally, the result is evaluated by using microscopic methods. From this research, it was found that the laser cleaning of copper, silver and aluminum alloys is feasible with Q-switched Nd:YAG at 1064 nm. Also, higher level of corrosion and accretions requires higher laser intensity. For low corrosion level on copper alloys, a thin water film on the irradiated area is beneficial.
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