Colloidal chemistry techniques at elevated temperatures (250-300°C) have been used to synthesize big (up to 20 nm) quantum dots (QDs) based on indium antimonide (InSb). In respect to their optical and electrical characteristics, the obtained big QDs exhibit properties similar to those of QDs with usual dimensions (4-5 nm), except the spectral maximum of luminescence being shifted inadequately to the size difference. This circumstance, together with the QD shape as measured by transmission electron microscopy, can be indicative of a less perfect crystalline structure of obtained big QDs, probably resulting from insufficiently high temperature of synthesis.
Energy spectrum of indium antimonide (InSb) quantum dots (QD) was analyzed in this paper. Properties of energy spectrum levels were determined both by calculations and experiments using differential tunneling current-voltage characteristics (CVC) rated to static conductivity. It was confirmed that relatively large QD (size of about 20-25 nm) exhibit quantum size effects. Critical values of the characteristic parameters of InSb QD are analyzed, in which application of the differential tunneling current-voltage characteristics method for express analysis of the characteristic sizes of QD leads to significant errors (more than 10 %).
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