Thin film conducting polymer thiophene based that is poly(3,4-ethylenedioxythiophene): poly(styrene sulphonic acid) (PEDOT:PSS) blended with Polyaniline (PANi) have been prepared with different composition by using drop casting technique. The optical characterization has been done by analyzing the absorbance spectra in the wavelength 300 to 800 nm. The electronic parameters were calculated by using Tauc/Davis-Mott Model. The results obtained showed that the absorbance, optical energy and Urbach energy were dependence on the ratio of PEDOT: PSS to PANi compositions.
A Polymer blends compose of Poly (3,4-ethylenedioxythiophene):Poly (styrene sulphonic acid)(PEDOT:PSS) and Polyaniline (PANi) have been prepared using drop casting technique. Optical parameters such as refractive index (n), extinction coefficient (k), reflectance, and optical dielectric were determined in this study. It is found that reflectance spectra increase as the PANi concentration decreases in the sample of small photon energy. The refractive index of the sample shows significant effect with the PEDOT:PSS concentration. As the concentration of PEDOT:PSS increases, the refractive index shows a normal dispersion behavior. Extinction coefficient decrease as the wavelength increase within the range of 300 nm to 350 nm that may contribute to the loss fraction of light due to scattering and the decreasing of absorbance at this range. However, the extinction coefficient increases from 350 nm to the maximum wavelength of 800 nm since the absorbance is also increasing. Both the real and imaginary part of the dielectric constant decreases when the photon energy increases. This revealed that the compositions of PEDOT:PSS influence the optical properties of hybrid PEDOT-PSS:PANi thin film.
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