The analysis of the cracking products of bitumen Karmalskoye deposits (the content of fractions boiling up to 200 °C 6,7% wt.) has been performed. The influence of power plant coal ash microspheres on orientation of cracking bitumen components is stated. Bitumen cracking leads to significant yields of gas and coke for more than 20% wt. and destructions of all components. The initiated bitumen cracking in the presence of 10% microspheres at cracking temperature 450 °C leads to reduction of gas and coke yields and increase in fractions of ibp (initial boiling point) –360 °C at 10% wt. in comparison with products of the thermal bitumen cracking. The analysis of composition and amount of sulfur compounds in initial bitumen and the cracking products in the various conditions has shown that the thermal cracking leads to increased homologues benzothiophene contents due to partial destruction of resins, and to decrease in the content of homologues dibenzothiophene
The results analysis of fractional and material composition of the cracking products of Ashalchinskoye and Karmalskoye bitumen deposits was presented in this work. The effect of bitumen ozone-oxygen mixture pretreatment followed by cracking on thermolysis processes was investigated. It was shown that molecules of resins and asphaltenes containing large amounts of aliphatic fragments in its structure readily undergo thermal decomposition to form additional distillate fractions. Low content of aliphatic fragments leads to aromatization of the naphthenic cycles in the molecule of resins and asphaltenes, the thermal degradation reactions proceed in high yields of gas and coke
Modern methods of recycling organic waste are not considered viable today. Therefore, an important advantage of the proposed technology is to obtain mineral fuel products as an output. The technologies of high-temperature processing are based on thermal decomposition of waste without oxygen at high temperature. In pyrolysis, wastes are converted into gaseous, liquid and solid fuels. Thereby, the properties and composition of the liquid feedstock obtained by pyrolysis with a boiling temperature in the range of X.I. (38) - 180 °C, 180 - 320 °C and more than 320 °C were investigated. Residue with a boiling temperature over 320° C (52.4% vol.) is the main portion of the synthetic liquid fuels (SLF). It can be attributed to fuel oil grade 100 and used as boiler fuel or fuel oil additives according to the studied physicochemical parameters
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