Force constants have been calculated for the out-of-plane bending motions of the vinyl halides and for cis- and trans- 1,2-dichloroethylene. Published vibrational assignments have been followed for the most part, but several changes were found necessary. A generally consistent set of force constants was obtained in which the values are also similar to those for the methyl halides.
A method involving three computer programs is described for characterizing the major component of the Sf 0–12 low‐density lipoprotein class by its Sf rate, hydrated density and molecular weight. All necessary information is obtained from a standard low and high‐density lipoprotein ultracentrifugal analysis. Moving‐boundary flotation rates are measured in 1.061 g/ml sodium chloride and 1.200 g/ml sodium bromide solutions and are corrected to flotation at zero concentration. Hydrated densities are calculated from η Fo versus ρ plots and minimum hydrated molecular weights calculated using Stokes' frictional factor, assuming spherical molecules. Preliminary application of this procedure indicates higher Sfo rates, higher molecular weights, and lower hydrated densities in females than in males. Molecular weights and standard deviations of the principal Sf 0–12 component for non‐fasting normal adult females and males were 2.36±0.16 and 2.12±0.20 millions, respectively.
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