E/Z-Furfurylalkenes from 2-Chloromethylfuran and Lithium Trialkylalkynylborates.-Reaction of 2-chloromethylfuran (I) with the lithium trialkylalkynylborates (II) followed by protonation leads to the formation of the E/Z-furfurylalkenes (III) with moderate E-stereoselectivity. -(LI, N.; CHEN, Y.; DENG, M.; Synthesis (1991) 1, 81-82; Shanghai Inst. Org. Chem.,
In this study, the mechanisms of CO2 formylation and methylation with N-methylaniline and PhSiH3 were investigated using density functional theory (DFT) calculations, and the chemical selectivity of the reaction towards...
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