This research is focused on the synthesis and the ability to inhibit scale and corrosion of poly(acrylic acid-co-acrylamide) (PAA-AM copolymers). A series of polymers were synthesized by free radical polymerization having various weight ratios of acrylic acid (AA) to acrylamide (AM). The structures of the synthesized polymers were characterized by UV-Vis Spectroscopy, FT-IR, and 1H-NMR. The thermal stability of the polymers was analyzed by a TGA technique. The water solubility of the polymers was examined using a turbidity meter. The scale inhibition performance test was performed by titration of calcium ion with ethylene diamine tetraacetic acid (EDTA) solution. After that, the crystal structure of CaCO3 scale from the scale inhibition test was examined using a scanning electron microscope. The efficiency of the corrosion inhibitor on low carbon steel AISI 1018 was investigated by a potentiodynamic polarization technique. The result show that PAA-AM copolymers having a 9:1 weight ratio with 45.82% at 100 ppm inhibited scale forming. The corrosion resistance of all inhibitors could be achieved when the concentration of the inhibitor was lower than 100 ppm.
요 약. 염료감을 태양전지(DSSC)는 대체에너지 집적제로서 낮은 생산단가로 고에너지 전환 효과를 볼 수 있다. 친환경 적이며 효과가 큰 무금속 염료감응제의 개발이 중요하다. 본 연구에서 유기 감광제로주제어: 유기염료 감응제, 집광 소재, 염료감응 태양전지 ABSTRACT. Dye-sensitized solar cell (DSSC); an alternate energy source harvester has gained some attractive features such as high-energy conversion efficiency low production cost. Dye-sensitizer is a basic component of DSSC, which affecting the performance of the energy conversion efficiency. Current research has been focusing on development of high efficiency, metal-free dye-sensitizers, which would be more environmental friendly. We had successfully explored synthetic route to 6,6'-(1,2,5-oxadiazole-3,4-diyl)dipyridine-2,4-dicarboxylic acid (3A) which has been used as organic sensitizer. Investigation of light conversion efficiency (η) of the compound uses standard measurement condition (one sun simulated irradiation, AM 1.5, 100 mW/cm 2 ) showed that it could reach 1.00% (JSC=2.63 mAcm -2 , VOC=0.64 V and FF=0.59). Under the same conditions, the ruthenium complex (N719) gave the conversion efficiency as high as 4.02%(JSC=10.50 mAcm -2 , VOC=0.67V and FF=0.57).
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