In this work, a study was made of methods for converting a real gas from a full-scale compressor to a model one for low-temperature pure methane using the equations of state of a real gas Benedict-Webb-Rubin and Peng-Robinson. In the course of the work, the features of recalculation methods were studied, a model of an air compressor was selected, corresponding in parameters to a model of a low-temperature methane compressor using the theory of similarity, using similarity criteria. Also, in this work, the features of the application of various equations of state were studied when describing the model of a low-temperature methane compressor, as well as the features that arise when this model is converted to an air model analogue. Data were obtained on the possibility of applying the proposed methods on real units, and the invariance of the method with respect to the used equations of state of a real gas for pure methane at temperatures from 150 to 300 K and a division of 0.2 MPa was proved. At the final stage of the work, comparative characteristics of two models of natural methane compressors were obtained, based on different equations of real gas, describing the medium and two models of model compressors using air as a working medium and being model analogs of the above units.
In this paper, various real gas state equations are considered and their comparative analysis is carried out. The following state equations are studied in the work: Benedict-Webb-Rubin modification equation, Ridlich-Kwong Real Gas equation, Peng-Robinson Real Gas equation, and the modified Ridlich-Kwong real gas state equations proposed by Barsuk S.D. We have made a direct comparison of these calculation methods with most accurate identification. In addition, the paper analyzes the equations features, with applicability limits definition of each state equations. For the chosen one, as the most universal and exact equation, the calculations were made for the liquid phase and the real gas two-phase state. Based on the data obtained, polynomials were developed for various parameters depending on the gas temperature, which can later be used to build various mathematical models. Our conclusions show main advantages of selected equation for real gases and the reasons for choosing it for modeling low-temperature heat and mass transfer processes.
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