A wideband near-IR (NIR) luminescence centered at 1080 nm was found in a RbPb(2)Cl(5):Bi single crystal grown by the Bridgman technique. Absorption, luminescence, and excitation of luminescence spectra were investigated at room and cryogenic temperatures. The luminescence was proposed to be due to the (3)P(1)-->(3)P(0) transition in Bi(+) ion.

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Microstructured crystalline optical fiber from silver halides is described. Both experimental and theoretical evidences are presented to establish that the fiber is effectively single mode at wavelength 10.6 micro m with numerical aperture NA=0.16 and optical losses of approximately 2 dB/m. Crystalline microstructured optical fibers offer key advantages over step-index optical fibers from silver halide crystals. The wide transmission range of wavelengths 2-20 micro m provides great potential for applications in spectroscopy and for the development of a range of new crystalline-based nonlinear optical fibers.