In this work, the perovskite LaMnO3 material has been prepared based on the sol-gel process of synthesis with the participation of combustion. According to the X-ray phase analysis, it was determined that the obtained material consists of LaMnO3 one phase (space group Pm-3m). Nevertheless, it has been determined that the average size of the coherent scattering region of the obtained material is about 24 nm. Moreover, the average particle size is 40-60 nm in case the approximation that the particles are spherical shape. Thus, it has been determined that the specific surface area of the material is 42.1 m2/g. The electrochemical investigations have been performed using nanosized LaMnO3 powder as a cathode material for electrochemical capacitors. The LaMnO3 material under research showed a specific capacity of 40 F/g at a discharge of up to 1V.
The paper is devoted to the study of the behavior of capacitor type electrochemical system in the К+-containing aqueous electrolytes. Nanoporous carbon material (NCM) was used as the electrode material, obtained by carbonization of plant raw materials with the following chemical activation. Optimization of pore size distribution was carried out by chemical-thermal method using potassium hydroxide as activator. It is shown that obtained materials have high values of capacitance which is realized by charge storage on the electrical double layer and by pseudocapacitive ion storage on the surface of the material. It is established that based on NCM, electrochemical capacitors are stable in all range of current density and material capacity essentially depends on appropriate choice of electrolyte.
sn this workD we hve otined nnoporous ron mteril @gwA from wlnut shells using the method of therml roniztionF woreoverD the in)uene of the roniztion temperture of the rw mteril on the eletril ondutivity of the gw otined y mnD infrred @sAD nd impedne spetrosopy hs een investigtedF gonsequentlyD to nlyze the evolution of the eletril ondutivity of the mteril with n inrese in the roniztion tempertureD the theory of peroltion hs een ppliedF Key words: ron nnoporous mterilD eletril ondutivityD impedne spetrosopyD mn spetrosopyD s spetrosopyF hysX httpsXGGdoiForgGIHFQHWUHGjpsFPSFQVHI I.
A research is done to characterize the microporous structure of outgoing and thermally modified (673 K, 180 min) plant-extracted carbon material. The porous system characteristics are worked out by different methods on low temperature (77K) N2 adsorption-desorption based isotherm. It is stated that thermal modification contributes to the enlargement of specific surface (from 361 m2/g to 673 m2/g), an increase in total pore volume (from 0,166 cm3/g to 0,477 cm3/g) and an increase in micropore volume (from 0,127 cm3/g to 0,173 cm3/g). Most effectively thermal modification is apt to form nanopores with diameters of 0,75; 1,25 and 4 nm.
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