In the present work the existence of a common compression factor
point for binary mixtures has been
investigated, both experimentally and theoretically. We found that
the linear isotherm regularity (LIR) is
able to predict the common compression factor point and the common bulk
modulus point for binary mixtures,
as well as pure dense fluids. An important conclusion deduced from
this work is that a physical interpretation
for such points may be given using LIR. The LIR along with the
mean geometric approximation (MGA)
have been used to relate the density at the common points of a mixture
to those of its pure components. The
numerical investigation shows that such a relation may be represented
by a quadratic function in terms of the
system composition for most mixtures. However, we have found that
such a quadratic relation is generally
valid for all investigated mixtures. An important result obtained
from this work is that we may get information
about the magnitude of interactions between unlike molecules, compared
to those of like interactions. Such
a result can be used to predict the deviation of a solution from
ideality without having any vapor pressure
data.
scite is a Brooklyn-based organization that helps researchers better discover and understand research articles through Smart Citations–citations that display the context of the citation and describe whether the article provides supporting or contrasting evidence. scite is used by students and researchers from around the world and is funded in part by the National Science Foundation and the National Institute on Drug Abuse of the National Institutes of Health.