The two complementary technologies of colloidal upconverting nano-emitters and maskless photolithography are exploited to fabricate nano-engineered optically-active surfaces for anticounterfeiting applications based on multipho ton absorption phenomenon in lanthanide 1 nanocomposites with a visualization wavelength in the NIR. It is demonstrated that the unique optical, thermal, and temporal characteristics of these versatile upconverting surface distinguishes them from their counterparts. A unique behaviour that is captured is the ability to actively tune their emission color by modifying the pumping power, temperature, and excitation frequency. A new low-cost negative photoresist is employed for implementation of maskless photolithography of single and double-color labels using two efficient upconverting nanocomposites based on NaYF4:Yb 3+ ,Er 3+ and NaYF4:Yb 3+ ,Tm 3+ nano-emitters. What's more, it is shown that the detectability of the proposed anti-counterfeiting approach can be carried out using just a smartphone. Each of the emission peaks of the upconversion nanoparticles is associated with a different multiphoton absorption mechanism and their thermosensitivity varies from one peak to another. Furthermore, their photoluminescent color changes by scanning the excitation beam impinging on the surfaces comprised of both upconversion nanoparticles doped in the UV-curable resist. Longterm photostability of these surfaces under continuous excitation by a high power laser makes them a promising nano-emitters for the next generation of anti-counterfeiting labels
scite is a Brooklyn-based organization that helps researchers better discover and understand research articles through Smart Citations–citations that display the context of the citation and describe whether the article provides supporting or contrasting evidence. scite is used by students and researchers from around the world and is funded in part by the National Science Foundation and the National Institute on Drug Abuse of the National Institutes of Health.