Olive mill wastewater (OMW), are the liquid residues generated during the extraction of oil by traditional and modern three-phase type crushing units. These effluents are characterized by an acidic pH and composition rich in water, organic matter, minerals and polyphenols. In general, they are directly discharged into natural ecosystems. Their danger is linked to the enormous quantities produced in a short period between October and March. To mitigate the effects of vegetable waters on the environment, their valorization in different areas is discussed. As biopesticides, crude OMW have been shown to be very toxic to Aphis pomi; the LC50 and LC95 varied respectively from 27.17 to 45.59 and from 77.19 to 134.57 mg of OMW/L of water; they vary according to the stage of the aphid considered. The young stages of A. pomi were more sensitive than the elderly are. Therefore, the OMW can be used as a means of controlling aphids. However, before operating on a large scale, it is necessary to repeat the trials in field and assess their impact on non-target organisms and treated crops.