Using energy-filtered transmission electron microscopy we measured surface-plasmon resonances of gold nanoplatelets with different shapes and edge lengths at high spatial resolution. We find equidistant maxima of the energy-loss probability along the platelet edges. The plasmon dispersion of the different geometries is very similar, i.e., hardly dependent on specimen shape. The experimental results are verified by means of finite-difference time-domain calculations which reveal the presence of wedge-plasmon polaritons propagating along the platelet edges. At platelet corners, apart from radiative losses, wedge-plasmon polaritons are partially reflected or transmitted to neighboring edges. The interference of all these contributions leads to the observed plasmon resonance modes. This is an essential step towards a thorough understanding of plasmon eigenmodes in prismatic nanoplatelets.
Hyperbolic media exhibit unparalleld properties, e.g, as light absorbers in photovoltaics and photonics, as superlenses in far-field imaging, as subwavelength light concentrators in nanolithography, or as novel materials in emission engineering. With the advent of optical metamaterials, deliberate design of material properties became possible. However, inadvertent variability in fabrication techniques and other factors limit performance characteristics of man-made hyperbolic materials. Here, we draw attention to a class of natural hyperbolic materials, the tetradymites. From generalized spectroscopic ellipsometry we extract the dielectric tensor components and find hyperbolic behavior in Bi2Se3 and Bi2Te3 in the near-infrared to visible spectrum. Previously, natural hyperbolic media were known only in the far-infrared spectral range. As possible applications of tetradymites we discuss superlenses for near-field microscopy and far-field isoindex filters. Solid solutions of tetradymites are likely tunable in operational wavelength from the infrared to the visible, complementing hyperbolic metamaterials.
Dipole selection rules underpin much of our understanding in characterization of matter and its interaction with external radiation. However, there are several examples where these selection rules simply break down, for which a more sophisticated knowledge of matter becomes necessary. An example, which is increasingly becoming more fascinating, is macroscopic toroidization (density of toroidal dipoles), which is a direct consequence of retardation. In fact, dissimilar to the classical family of electric and magnetic multipoles, which are outcomes of the Taylor expansion of the electromagnetic potentials and sources, toroidal dipoles are obtained by the decomposition of the moment tensors. This review aims to discuss the fundamental and practical aspects of the toroidal multipolar moments in electrodynamics, from its emergence in the expansion set and the electromagnetic field associated with it, the unique characteristics of their interaction with external radiations and other moments, to the recent attempts to realize pronounced toroidal resonances in smart configurations of meta-molecules. Toroidal moments not only exhibit unique features in theory but also have promising technologically relevant applications, such as data storage, electromagnetic-induced transparency, unique magnetic responses and dichroism.
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