Natalya V. Kirij scite author profile

Tris(trifluormethyl)(triphenylphosphan)palladat(II) und —platinat(II), [M(CF3)3(PPh3)]—, und die Tetrakis(trifluormethyl)metallate(II), [M(CF3)4]2— (M = Pd, Pt), entstehen bei den Reaktionen von [MCl2(PPh3)2] mit Me3SiCF3 / [Me4N]F oder mit [I(CF3)2]—‐Salzen in guten Ausbeuten. [Me4N][M(CF3)3(PPh3)] kristallisieren isotyp in der orthorhombischen Raumgruppe Pnma (Nr. 62) mit Z = 4. Die NMR‐Spektren der neuen Verbindungen werden beschrieben.

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Tetramethylammonium trifluoromethyltellurate(0), [NMe4]TeCF3, synthesis, characterisation and properties

Tyrra

Kirij

Naumann

et al. 2004

Journal of Fluorine Chemistry

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Convenient syntheses of 1,1,1,3,3,3-hexafluoro-2-organyl-propan-2-ols and the corresponding trimethylsilyl ethers

et al. 2005

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Natalya V. Kirij

[Me3Si(CF3)F]− and [Me3Si(CF3)2]−: Reactive Intermediates in Fluoride-Initiated Trifluoromethylation with Me3SiCF3— An NMR Study

Synthesen und Charakterisierungen der ersten Tris‐ und Tetrakis(trifluormethyl)palladate(II) und ‐platinate(II), [M(CF₃)₃(PPh₃)]^— und [M(CF₃)₄]^2— (M = Pd, Pt)

Tetramethylammonium trifluoromethyltellurate(0), [NMe4]TeCF3, synthesis, characterisation and properties

Convenient syntheses of 1,1,1,3,3,3-hexafluoro-2-organyl-propan-2-ols and the corresponding trimethylsilyl ethers

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Natalya V. Kirij

[Me3Si(CF3)F]− and [Me3Si(CF3)2]−: Reactive Intermediates in Fluoride-Initiated Trifluoromethylation with Me3SiCF3— An NMR Study

Synthesen und Charakterisierungen der ersten Tris‐ und Tetrakis(trifluormethyl)palladate(II) und ‐platinate(II), [M(CF3)3(PPh3)]— und [M(CF3)4]2— (M = Pd, Pt)

Tetramethylammonium trifluoromethyltellurate(0), [NMe4]TeCF3, synthesis, characterisation and properties

Convenient syntheses of 1,1,1,3,3,3-hexafluoro-2-organyl-propan-2-ols and the corresponding trimethylsilyl ethers

Contact Info

Product

Resources

About

Synthesen und Charakterisierungen der ersten Tris‐ und Tetrakis(trifluormethyl)palladate(II) und ‐platinate(II), [M(CF₃)₃(PPh₃)]^— und [M(CF₃)₄]^2— (M = Pd, Pt)