In analogy to transistors in classical electronic circuits, a quantum optical switch is an important element of quantum circuits and quantum networks [1][2][3]. Operated at the fundamental limit where a single quantum of light or matter controls another field or material system [4], it may enable fascinating applications such as long-distance quantum communication [5], distributed quantum information processing[2] and metrology [6], and the exploration of novel quantum states of matter [7]. Here, by strongly coupling a photon to a single atom trapped in the near field of a nanoscale photonic crystal cavity, we realize a system where a single atom switches the phase of a photon, and a single photon modifies the atom's phase. We experimentally demonstrate an atom-induced optical phase shift [8] that is nonlinear at the two-photon level [9], a photon number router that separates individual photons and photon pairs into different output modes [10], and a single-photon switch where a single "gate" photon controls the propagation of a subsequent probe field [11, 12]. These techniques pave the way towards integrated quantum nanophotonic networks involving multiple atomic nodes connected by guided light.A quantum optical switch [11,[13][14][15][16]] is challenging to implement because the interaction between individual photons and atoms is generally very weak. Cavity quantum electrodynamics (cavity QED), where a photon is confined to a small spatial region and made to interact strongly with an atom, is a promising approach to overcome this challenge [4]. Over the last two decades, cavity QED has enabled advances in the control of microwave [17][18][19] and optical fields [13,[20][21][22][23]. While integrated circuits with strong coupling of microwave photons to superconducting qubits are currently being developed [24], a scalable path to integrated quantum circuits involving coherent qubits coupled via optical photons has yet to emerge.Our experimental approach, illustrated in Figure 1a, makes use of a single atom trapped in the near field of a nanoscale photonic crystal (PC) cavity that is attached * These authors contributed equally to this work † vuletic@mit.edu ‡ lukin@fas.harvard.eduto an optical fiber taper [2]. The tight confinement of the optical mode to a volume V ∼ 0.4 λ 3 , below the scale of the optical wavelength λ, results in strong atom-photon interactions for an atom sufficiently close to the surface of the cavity. The atom is trapped at about 200 nm from the surface in an optical lattice formed by the interference of an optical tweezer and its reflection from the side of the cavity (see Methods Summary, SI and Fig. 1a,b). Compared to transient coupling of unconfined atoms [13, 22], trapping an atom allows for experiments exploiting long atomic coherence times, and enables scaling to quantum circuits with multiple atoms. We use a one-sided optical cavity with a single port for both input and output [8]. In the absence of intracavity loss, photons incident on the cavity are always reflected. However, a s...

Nuclear magnetic resonance spectroscopy is a powerful tool for the structural analysis of organic compounds and biomolecules but typically requires macroscopic sample quantities. We use a sensor, which consists of two quantum bits corresponding to an electronic spin and an ancillary nuclear spin, to demonstrate room temperature magnetic resonance detection and spectroscopy of multiple nuclear species within individual ubiquitin proteins attached to the diamond surface. Using quantum logic to improve readout fidelity and a surface-treatment technique to extend the spin coherence time of shallow nitrogen-vacancy centers, we demonstrate magnetic field sensitivity sufficient to detect individual proton spins within 1 second of integration. This gain in sensitivity enables high-confidence detection of individual proteins and allows us to observe spectral features that reveal information about their chemical composition.

Hybrid quantum devices, in which dissimilar quantum systems are combined in order to attain qualities not available with either system alone, may enable far-reaching control in quantum measurement, sensing, and information processing. A paradigmatic example is trapped ultracold atoms, which offer excellent quantum coherent properties, coupled to nanoscale solid-state systems, which allow for strong interactions. We demonstrate a deterministic interface between a single trapped rubidium atom and a nanoscale photonic crystal cavity. Precise control over the atom's position allows us to probe the cavity near-field with a resolution below the diffraction limit and to observe large atom-photon coupling. This approach may enable the realization of integrated, strongly coupled quantum nano-optical circuits.

Metamaterials are artificial optical media composed of sub-wavelength metallic and dielectric building blocks that feature optical phenomena not present in naturally occurring materials. Although they can serve as the basis for unique optical devices that mould the flow of light in unconventional ways, three-dimensional metamaterials suffer from extreme propagation losses. Two-dimensional metamaterials (metasurfaces) such as hyperbolic metasurfaces for propagating surface plasmon polaritons have the potential to alleviate this problem. Because the surface plasmon polaritons are guided at a metal-dielectric interface (rather than passing through metallic components), these hyperbolic metasurfaces have been predicted to suffer much lower propagation loss while still exhibiting optical phenomena akin to those in three-dimensional metamaterials. Moreover, because of their planar nature, these devices enable the construction of integrated metamaterial circuits as well as easy coupling with other optoelectronic elements. Here we report the experimental realization of a visible-frequency hyperbolic metasurface using single-crystal silver nanostructures defined by lithographic and etching techniques. The resulting devices display the characteristic properties of metamaterials, such as negative refraction and diffraction-free propagation, with device performance greatly exceeding those of previous demonstrations. Moreover, hyperbolic metasurfaces exhibit strong, dispersion-dependent spin-orbit coupling, enabling polarization- and wavelength-dependent routeing of surface plasmon polaritons and two-dimensional chiral optical components. These results open the door to realizing integrated optical meta-circuits, with wide-ranging applications in areas from imaging and sensing to quantum optics and quantum information science.

We investigated the effect of substrate-induced strain on the metal-insulator transition (MIT) in single-crystalline VO(2) nanobeams. A simple nanobeam-substrate adhesion leads to uniaxial strain along the nanobeam length because of the nanobeam's unique morphology. The strain changes the relative stability of the metal (M) and insulator (I) phases and leads to spontaneous formation of periodic, alternating M-I domain patterns during the MIT. The spatial periodicity of the M-I domains can be modified by changing the nanobeam thickness and the Young's modulus of the substrate.