In this work, a novel photocatalytic reactor for the pulsed and controlled excitation of the photocatalyst and the precise deposition of metallic nanoparticles is developed. Guidelines for the replication of the reactor and its operation are provided in detail. Three different composite systems (Pt/graphene, Pt/TiO 2 , and Au/TiO 2 ) with monodisperse and uniformly distributed particles are produced by this reactor, and the photodeposition mechanism, as well as the synthesis optimization strategy, are discussed. The synthesis methods and their technical aspects are described comprehensively. The role of the ultraviolet (UV) dose (in each excitation pulse) on the photodeposition process is investigated and the optimum values for each composite system are provided.
Increasing the efficiency of electrocatalyst is the key demand for the polymer electrolyte membrane fuel cells (PEMFC). To address the activity and performance challenges of commercial electrocatalyst, Pt/C, we introduce a new hybrid catalyst support for Pt nanoparticles. In this regard, combining or mixing specific type of carbon-based supports is a feasible strategy to increase catalyst utilization and performance. In the current study, Pt nanoparticles (NPs) were decorated on a new hybrid network, comprising of carbon nanofiber (CNF) and carbon black (CB), by means of a facile and efficient microwave (MW) assisted reduction method. All synthesized electrocatalysts were characterized to elucidate chemical and morphological structures. Then, the hybrid electrocatalysts were utilized as hydrogen oxidation reaction (HOR) and oxygen reduction reaction (ORR) electrocatalysts and their electrocatalytic activities were investigated by using cyclic voltammetry (CV) and linear sweep voltammetry (LSV), respectively. We found that the hybridization of CNF with CB substantially improved not only the electrocatalytic activity but also the fuel cell performance, which can be attributed to a consecutive conductive network, in which CB acts as a spacer, and synergistic effects between the CNF and CB. The hybrid electrocatalyst (Pt/CNF-CB with 50:50 wt%) showed a superior activity toward HOR and ORR while also offering exceptional fuel cell performance. That hybrid possessed the highest electrochemically active surface area (ECSA) compared with Pt/CNF and Pt/CB. In addition, the mass activity (at 0.80 V vs RHE) of the Pt/CNF-CB (50:50 wt%) is about 3.3 and 3.5 times higher than that of Pt/CNF and Pt/CB, respectively. Furthermore, that hybrid electrocatalyst exhibited enhanced fuel cell performance with 907 mW. cm −1 maximum power density. This work demonstrated that the CNF-CB supported Pt nanoparticles as electrocatalysts are extremely promising for fuel cell reactions.
Summary
This study demonstrated the capability of a novel method in controlling the structural and electrochemical properties of electrocatalysts, utilizing a pulsed‐ultraviolet (UV) setup for the synthesis procedure. A hand‐made reactor provided a new set of parameters. The variation of UVon and UVoff periods resulted in samples with a range of different structures, compositions, and activities. Graphene/Pt was prepared with varying forms of illumination pulse, and its hydrogen oxidation and oxygen reduction reaction performances were evaluated. Controlling the reduction degree of Pt ions on partially reduced graphene oxide was achieved by manipulating the setup design. The results revealed a dominant growth and agglomeration phase of Pt particles, mostly with metallic states, by increasing both UVon and Uoff time spontaneously. Long UVon without adequate UVoff did not result in promising electrocatalytic activities. In other words, different structures, compositions, and activities of samples suggested that not just the illumination is the crucial factor, it is also the resting time or UVoff which determines the surface adsorption kinetics, nucleation sites, and growth mechanism of nanoparticles. Further chemical reduction by highly concentrated ascorbic acid was used to confirm the proposed mechanisms, which lead to samples even with more metallic Pt (Pt0).
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