Coal fly ash is found to be one of the key pollutants worldwide due to its toxic heavy metal content. However, due to advancements in technology, coal fly ash has gained importance in various emerging fields. They are rich sources of carbonaceous particles which remain unburnt during burning of various coals in thermal power plants (TPPs). Various carbonaceous nanoparticles in the form of fullerenes, soot, and carbon nanotubes could be recovered from coal fly ash by applying trending techniques. Moreover, coal fly ash is comprised of rich sources of organic carbons such as polycyclic and polyaromatic hydrocarbons that are used in various industries for the development of carbon-derived value-added materials and nanocomposites. Here, we focus on all the types of carbon nanominerals from coal fly ash with the latest techniques applied. Moreover, we also emphasize the recovery of organic carbons in polyaromatic (PAHs) and polycyclic hydrocarbons (PCHs) from coal fly ash (CFA). Finally, we try to elucidate the latest applications of such carbon particle in the industry.

Re-utilization of waste for fabricating photocatalyst to treat polluted water.

Nano-fibrillated cellulose (NFC) was extracted by a chemical method involving alkali and acid hydrolysis. The characterisation of the citrus sinensis fruit peel bran and nano-fibrillated cellulose was performed by XRD, FTIR, TEM, and FESEM. XRD confirmed the phase of NFC which showed monoclinic crystal with spherical to rod shape morphology with a size of 44–50 nm. The crystallinity index of treated NFC increased from 39% to 75%. FTIR showed the removal of lignin and hemicellulose from waste peels due to the alkaline treatment. Silver nanoparticles were also synthesised by utilizing extract of citrus sinensis skins as a reducing agent. Pharmaceutical effluent samples from an industrial area were tested by Atomic Absorption Spectrometry. Out of the four metals obtained, cadmium and chromium were remediated by silver nanoparticles with nano-fibrillated cellulose via simulated method in 100 mg/L metal-salt concentrations over a time period of 160 min. The highest removal efficiency was found for cadmium, i.e., 83%, by using silver and NFC together as adsorbents. The second highest was for chromium, i.e., 47%, but by using only NFC. The Langmuir and Freundlich isotherms were well fitted for the sorption of Cd (II) and Cr (II) with suitable high R2 values during kinetic simulation. Thus, the isolation of NFC and synthesis of silver nanoparticles proved efficient for heavy metal sorption by the reuse of waste skins.

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