The 2022 Roadmap is the next update in the series of Plasma Roadmaps published by Journal of Physics D with the intent to identify important outstanding challenges in the field of low-temperature plasma (LTP) physics and technology. The format of the Roadmap is the same as the previous Roadmaps representing the visions of 41 leading experts representing 21 countries and five continents in the various sub-fields of LTP science and technology. In recognition of the evolution in the field, several new topics have been introduced or given more prominence. These new topics and emphasis highlight increased interests in plasma-enabled additive manufacturing, soft materials, electrification of chemical conversions, plasma propulsion, extreme plasma regimes, plasmas in hypersonics, data-driven plasma science and technology and the contribution of LTP to combat COVID-19. In the last few decades, LTP science and technology has made a tremendously positive impact on our society. It is our hope that this roadmap will help continue this excellent track record over the next 5–10 years.

Obtaining high yields in agricultural production is essential due to the world's population growth and increased food demand. At the same time, adverse effects of agriculture on the environment need to be kept to a minimum. Low temperature plasmas (LTPs) show promise as efficient green technologies for enhancing productivity while maintaining good food quality and safety in the many steps of the food cycle. As a result, applications of LTPs in agriculture have led to creation of a new, rapidly developing field called “plasma agriculture.” Here, we briefly overview the state‐of‐the‐art of LTP applications in the complete food cycle, that is, in treatments of seeds, plants, and food.

The interest in plasma-activated water (PAW) has been greatly increasing during the last few years due to its potential applications in biological and medical sciences, as well as in agriculture and food industry. The effect of PAW is caused by the reactive oxygen and nitrogen species (RONS) generated in the liquid exposed to plasma. This work reviews recent research on the formation of reactive nitrogen species (RNS) in aqueous solutions treated by non-thermal plasma. The most important chemical reactions leading to the production of these active species in the gas and liquid phase, as well as their chemistry in the liquid, correlated with their lifetime are addressed. The literature data on the most important long-lived RNS in PAW (nitrite and nitrate) and the short-lived ones (peroxynitrite and peroxynitrate) are reviewed. The reported results show that their concentrations strongly depend on the type of electrical discharge, gas composition, liquid properties and treatment conditions, and thus tuning the PAW composition over a relatively wide range can be achieved. Results on the possible application of PAW in agriculture are also reviewed. The role of RNS in this area is related to their participation in various signalling pathways in plants, which regulate metabolic processes, plant development, response to stress, etc, and thus can finally lead to enhanced germination and/or faster germination process and increase in plant growth.

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