It is essential to know the behavior of the battery at all relevant internal and external conditions when the battery cell is in the new and the aging state. Electrochemical impedance spectroscopy (EIS) is a viable approach that can be used in lithium ion batteries (LIBs) to investigate the electrochemical behavior. In this paper, in order to investigate the state of charge effects on the LIBs, three types of commercial LIB cells were used, and the EIS measurements were performed under 100%, 80%, 50%, 20% and 0% SOC, respectively. An equivalent circuit model (ECM) including two constant phase angle elements in parallel with resistor elements is established to study the impedance characteristics for LIBs. The influence of the state of charge on the parameters of the ECM was analyzed. Based on the results we think EIS combined with ECM simulation tool can be used to derive useful information for improving battery design and state of health prediction.
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