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Niobium doped lead‐tin‐zirconate‐titanate ceramics near the PZT 95/5 orthorhombic AFE – rhombohedral FE morphotropic phase boundary Pb1‐0.5y(Zr0.865‐xTixSn0.135)1‐yNbyO3 were prepared according to a 22+1 factorial design with x = 0.05, 0.07 and y = 0.0155, 0.0195. The ceramics were prepared by a traditional solid‐state synthesis route and sintered to near full density at 1250°C for 6 h. All compositions were ∼98% dense with no detectable secondary phases by X‐ray diffraction. The ceramics exhibited equiaxed grains with intergranular porosity, and grain size was ∼5 µm, decreasing with niobium substitution. Compositions exhibited remnant polarization values of ∼32 µC/cm2, increasing with Ti substitution. Depolarization by the hydrostatic pressure induced FE‐AFE phase transition was drastically affected by variation of the Ti and Nb substitution, increasing at a rate of 113 MPa /1% Ti and 21 MPa/1% Nb. Total depolarization output was insensitive to the change in Ti and Nb substitution, ∼32.8 µC/cm2 for the PSZT ceramics. The R3c‐R3m and R3m‐Pm3m phase transition temperatures on heating ranged from 90 to 105°C and 183 to 191°C, respectively. Ti substitution stabilized the R3c and R3m phases to higher temperatures, while Nb substitution stabilized the Pm3m phase to lower temperatures. Thermal hysteresis of the phase transitions was also observed in the ceramics, with transition temperature on cooling being as much as 10°C lower.

Niobium (Nb)-doped lead-tin-zirconate-titanate (PSZT) ceramics near the leadzirconate-titanate 95/5 orthorhombic AFE-rhombohedral FE morphotropic phase boundary (PSZT 13.5/81/5.5 -1.6Nb) were prepared with up to 10 mol.% of hafnium (Hf) substituted for zirconium. The ceramics were prepared by a traditional solid-state synthesis route and sintered to near full density at 1150 • C for 6 h in sealed alumina crucibles with self-same material as the lead vapor source. All compositions were ∼98% dense with no detectable secondary phases by X-ray diffraction. The grain size was ∼3 μm for all compositions, consisting of equiaxed grains with intergranular porosity. The compositions exhibited remnant polarization values of ∼32 μC/cm 2 . Depolarization by the hydrostatic pressure-induced FE-AFE phase transition occurred at 310 MPa for all compositions, resulting in a total depolarization output of 32.4 μC/cm 2 for the PSZT ceramics. Evaluation of the R3c-R3m and R3m-Pm 3 m phase transition temperatures by impedance spectroscopy showed temperatures on heating ranging from 86 to 92 • C and 186 to 182 • C, respectively, for increasing nominal Hf content. Thermal hysteresis of the phase transitions was also observed in the ceramics, with the transition temperature on cooling being 1-4 • C lower. The study demonstrated that the PSZT ceramics are relatively insensitive to variations in Hf content in the range of 0 to 10 mol.%.