Encapsulation of ionic liquids (ILs) has been shown to be an effective technique to overcome slow mass transfer rates and handling difficulties that stem from the high viscosity of bulk ILs. These systems commonly rely on diffusion of small molecules through the encapsulating material (shell), into the IL core, and thus the composition of the shell impacts uptake performance. Herein, we report the impact of polymer shell composition on the uptake of the small molecule dye methyl red from water by encapsulated IL. Capsules with core of 1-hexyl-3-methylimidazolium bis(trifluorosulfonyl)imide ([Hmim][TFSI]) were prepared by interfacial polymerization in emulsions stabilized by graphene oxide (GO) nanosheets; the use of different diamines and diisocyanates gave capsule shells with polyureas that were all aliphatic, aliphatic/aromatic, and aliphatic/polar aprotic. These capsules were then added to aqueous solutions of methyl red at different pH values, and migration of the dye into the capsules was monitored by UV–vis spectroscopy, compared to the capsule shell alone. Regardless of the polymer identity, similar extents of dye uptake were observed (>90% at pH = 2), yet capsules with shells containing polyureas with polar aprotic linkages took longer to reach completion. These studies indicate that small changes in capsule shell composition can lead to different performance in small molecule uptake, giving insight into how to tailor shell composition for specific applications, such as solvent remediation and gas uptake.

Thermal conductivity is generally the tool of choice for quantification of fixed gases, particularly lighter-than-air gases. Unfortunately, gas chromatography-thermal conductivity detectors (GC-TCDs) are difficult to introduce in first- and second-year chemistry courses where the cost and number of instruments, as well as the space required, is impractical. In this article, the authors describe the development of a small, inexpensive microcontroller-based TCD for undergraduate teaching and research laboratory experiments which utilizes a matched pellistor pair to quantify hydrogen. The total cost of materials is under $200, including the microcontroller, electronics, TCD pellistor pair, and the mechanical parts which serve as the housing and analysis chamber.

Nonflammable eutectic solvents show great potential to enhance the concentrations of the redox-active materials and the cell voltages for redox flow batteries (RFBs). Herein, we report a promising redox-active eutectic electrolyte (1.5 M total redox species) with viologen and ferrocene derivatives where both of the redox reactions are reversible with a maximum open-circuit voltage of 1.35 V and an energy density of 15.1 Wh L −1 , which is relevant to large-scale energy storage. The charge−discharge (from 75 to 25% state of charge) characteristics in a flow cell (0.15 M negolyte and 0.3 M posolyte) showed that it can be cycled with consistent discharge capacity for 12 h (19 cycles), beyond which pressure-driven crossover between the posolyte and negolyte reservoirs leads to capacity decay. This study points to promising new directions toward eutectic electrolyte development for RFBs where we demonstrate increasing the polarity, functionalizing the redox molecules, and separating redox intermediates to prevent undesired side reactions can make improvements in operating cell voltage, energy density, and cyclability.

Fluid-filled capsules and liquidous polymers are combined to produce 3D printable inks, enabling printing of fluid-containing monoliths with porous and nonporous microstructures.

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