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The research started from the fact that the coacervation process represents the process of formation of macromolecular aggregates after separation from the phase that takes place in a homogeneous polymer solution as a result of the addition of a non-solvent. This process is very complex, and takes place in several stages of emulsification technology. The first step of the research created a sample through an encapsulation process of complex coacervation, followed by the creation of three different samples with specific emulsification technologies. Each resulting sample and step of emulsification went through rheological analysis, including the development of evolutions of the complex viscosity, loss module and respective storage module. When we analyzed the rheological properties of each sample at different emulsification stages, we reached the conclusion that, at the moment when the polymerization reaction develops the methyl methacrylate (MMA), the loss modules of the samples were stronger than the storage modules. In this context, the emulsification technology strongly influenced the process of forming the polymethyl methacrylate (PMMA) layer over the butyl stearate particles. In addition, in order to obtain the corresponding microcapsules, it was preferable for the butyl stearate particles covered with MMA to be vigorously stirred in a short period of time, under 250 s, because after that the polymerization process of the MMA on the surface of the particles begins. When producing microcapsules, it is very important that the whole process of emulsification be accompanied by rigorous stirring.

Polylactic acid (PLA) is one of the most extensively used biodegradable aliphatic polyester produced from renewable resources, such as corn starch. Due to its qualities, PLA is a leading biomaterial for numerous applications in medicine as well as in industry, replacing conventional petrochemical - based polymers. The purpose of this paper is to highlight the mechanical properties, such as tensile stress, of pure PLA specimens in comparison with PLA based-composites, with three different added materials in PLA mass: Copper, Aluminum and Graphene, as well as the influence of filament angle deposition on these properties. In order to check if the the filling density of the specimen influences the ultimate tensile stress (UTS), three different filling percentages (60%, 80% and 100%) have been chosen in the experimental tests. In this context, the mechanical characteristics of four different filament types based on PLA material, starting from pure PLA to PLA with Aluminum, Copper or Graphene filler are compared. Understanding and controlling these parameters is essential for the successful use of PLA and PLA-based composites in different areas such as medical applications, sport equipments and light industry.These tests have been performed due to the fact there is a lack of information concerning the mechanical properties. In the scientific literature, such information is only available for expensive printing systems; for open source printers (as those used in these tests), the information is poor and for some new materials, even inexistant. According to the technical specifications, for an expensive printer the cost may exceed 3000 Euros, with a minimum layer resolution of 100 m, this type of printer can reliably reproduce many 3D objects accurately, in quiter conditions.

A very important issue that needs to be solved as simply and correctly as possible is how to establish the thermal performance of phase-changing materials (PCM). The undertaken researches have analyzed the values of the thermal performances of the PCM taking into account the method of finite elements and the experimental research, respectively, based on a modern measurement system that was designed and implemented. Butyl stearate which has been encapsulated through complex coacervation in polymethyl methacrylate has been used as a PCM. Samples were made containing 10%, 20%, 30% and 40% PCM, respectively, within their structure. The research has established that at both the hot plate and the cold plate interface, the evolution of the temperature over time, established by both the finite element method (FEM) and experimental research, are quite close, and the best results have been obtained for the P30 sample. A very important thing observed during the finite element method (FEM) is that the simulated thermal flow variation extends between 2700-3110W/m2 being small enough not to influence the temperature measurement at the interface of hot or cold plates. Thus, the use of the FEM or the experimental research method can be applied with good results, provided that the correct initial conditions are used in the finite element method and that the experimental research is performed using the best possible apparatus.

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