This paper presents a comprehensive assessment of real gas effects on the performance and matching of centrifugal compressors operating in supercritical CO2. The analytical framework combines first principles based modeling with targeted numerical simulations to characterize the internal flow behavior of supercritical fluids with implications for radial turbomachinery design and analysis. Trends in gas dynamic behavior, not observed for ideal fluids, are investigated using influence coefficients for compressible channel flow derived for real gas. The variation in the properties of CO2 and the expansion through the vapor-pressure curve due to local flow acceleration are identified as possible mechanisms for performance and operability issues observed near the critical point. The performance of a centrifugal compressor stage is assessed at different thermodynamic conditions relative to the critical point using computational fluid dynamics (CFD) calculations. The results indicate a reduction of 9% in the choke margin of the stage compared to its performance at ideal gas conditions due to variations in real gas properties. Compressor stage matching is also impacted by real gas effects as the excursion in corrected mass flow per unit area from inlet to outlet increases by 5%. Investigation of the flow field near the impeller leading edge at high flow coefficients shows that local flow acceleration causes the thermodynamic conditions to reach the vapor-pressure curve. The significance of two-phase flow effects is determined through a nondimensional parameter that relates the time required for liquid droplet formation to the residence time of the flow under saturation conditions. Applying this criterion to the candidate compressor stage shows that condensation is not a concern at the investigated operating conditions. In the immediate vicinity of the critical point however, this effect is expected to become more prominent. While the focus of this analysis is on supercritical CO2 compressors for carbon capture and sequestration (CCS), the methodology is directly applicable to other nonconventional fluids and applications.

This paper presents a design strategy for very low flow coefficient multistage compressors operating with supercritical CO2 for carbon capture and sequestration (CCS) and enhanced oil recovery (EOR). At flow coefficients less than 0.01, the stage efficiency is much reduced due to dissipation in the gas-path and more prominent leakage and windage losses. Instead of using a vaneless diffuser as is standard design practice in such applications, the current design employs a vaned diffuser to decrease the meridional velocity and to widen the gas path. The aim is to achieve a step change in performance. The impeller exit width is increased in a systematic parameter study to explore the limitations of this design strategy and to define the upper limit in efficiency gain. The design strategy is applied to a full-scale reinjection compressor currently in service. Three-dimensional, steady, supercritical CO2 computational fluid dynamics (CFD) simulations of the full stage with leakage flows are carried out with the National Institute of Standards and Technology (NIST) real gas model. The design study suggests that a nondimensional impeller exit width parameter b2* = (b2/R)ϕ of six yields a 3.5 point increase in adiabatic efficiency relative to that of a conventional compressor design with vaneless diffuser. Furthermore, it is shown that in such stages the vaned diffuser limits the overall stability and that the onset of rotating stall is likely caused by vortex shedding near the diffuser leading edge. The inverse of the nondimensional impeller exit width parameter b2* can be interpreted as the Rossby number. The investigation shows that, for very low flow coefficient designs, the Coriolis accelerations dominate the relative flow accelerations, which leads to inverted swirl angle distributions at impeller exit. Combined with the two-orders-of-magnitude higher Reynolds number for supercritical CO2, the leading edge vortex shedding occurs at lower flow coefficients than in air suggesting an improved stall margin.

This paper presents a comprehensive assessment of real gas effects on the performance and matching of centrifugal compressors operating in supercritical CO2. The analytical framework combines first principles based modeling with targeted numerical simulations to characterize the internal flow behavior of supercritical fluids with implications for radial turbomachinery design and analysis. Trends in gas dynamic behavior, not observed for ideal fluids, are investigated using influence coefficients for compressible channel flow derived for real gas. The variation in the properties of CO2 and the expansion through the vapor-pressure curve due to local flow acceleration are identified as possible mechanisms for performance and operability issues observed near the critical point. The performance of a centrifugal compressor stage is assessed at different thermodynamic conditions relative to the critical point using CFD calculations. The results indicate a reduction of 9% in the choke margin of the stage compared to its performance at ideal gas conditions due to variations in real gas properties. Compressor stage matching is also impacted by real gas effects as the excursion in corrected mass flow per unit area from inlet to outlet increases by 5%. Investigation of the flow field near the impeller leading edge at high flow coefficients shows that local flow acceleration causes the thermodynamic conditions to reach the vapor-pressure curve. The significance of two-phase flow effects is determined through a non-dimensional parameter that relates the time required for liquid droplet formation to the residence time of the flow under saturation conditions. Applying this criterion to the candidate compressor stage shows that condensation is not a concern at the investigated operating conditions. In the immediate vicinity of the critical point however, this effect is expected to become more prominent. While the focus of this analysis is on supercritical CO2 compressors for carbon capture and sequestration, the methodology is directly applicable to other non-conventional fluids and applications.

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This paper presents a design strategy for very low flow coefficient multi-stage compressors operating with supercritical CO2 for Carbon Capture and Sequestration (CCS) and Enhanced Oil Recovery (EOR). At flow coefficients less than 0.01 the stage efficiency is much reduced due to dissipation in the gas-path and more prominent leakage and windage losses. Instead of using a vaneless diffuser as is standard design practice in such applications, the current design employs a vaned diffuser to decrease the meridional velocity and to widen the gas path. The aim is to achieve a step change in performance. The impeller exit width is increased in a systematic parameter study to explore the limitations of this design strategy and to define the upper limit in efficiency gain. The design strategy is applied to a full-scale re-injection compressor currently in service. Three-dimensional, steady, supercritical CO2 CFD simulations of the full stage with leakage flows are carried out with the NIST real gas model. The design study suggests that a non-dimensional impeller exit width parameter b2* = (b2/R)ϕ of 6 yields a 3.5 point increase in adiabatic efficiency relative to that of a conventional compressor design with vaneless diffuser. Furthermore, it is shown that in such stages the vaned diffuser limits the overall stability and that the onset of rotating stall is likely caused by vortex shedding near the diffuser leading edge. The inverse of the non-dimensional impeller exit width parameter b2* can be interpreted as the Rossby number. The investigation shows that, for very low flow coefficient designs, the Coriolis accelerations dominate the relative flow accelerations, which leads to inverted swirl angle distributions at impeller exit. Combined with the two-orders-of-magnitude higher Reynolds number for supercritical CO2, the leading edge vortex shedding occurs at lower flow coefficients than in air suggesting an improved stall margin.