Metallized yarns have become an integral part of fashion because they give extra sheen to garments and an inimitable appearance to fabrics, making them special yarns. However, because of repetitive washing and abrasions, the metallic part of the yarn in the fabric is removed and the fabric loses its brightness and becomes transparent. This study aims to solve this issue by searching for high-quality metallized yarn production methods to eliminate problems during usage. In the experimental part of the study, eight different types of metallized films were produced using the lamination technique with two kinds of adhesives. Non-laminated metallized polyester films were used as a reference to understand the effectiveness of the lamination process. Metallized yarns were produced from laminated metallized films by using standard production parameters. After producing nine different types of metallized yarns, monotype knitted fabrics were then from these yarns. Yarn’s basic properties and fabric’s mechanical properties were then measured to compare the effect of the thin film type, lamination process and adhesive type effect on these properties. The test results showed that the lamination technique significantly improves the resistance of the repetitive washing process and the abrasion property of fabrics. The best results were obtained with polypropylene thin films. However, they had a higher friction coefficient and a harder handle property than polyester films. When using a thinner polypropylene film, this problem could be eliminated, and the yarns could be an important alternative choice for commercially producing metallized yarns in the future.
In this study, graphene oxide and aginate were used to synthesis of nanobiocomposites under different synthesis conditions and the used to investigate the adsorption properties of Th (IV) ions from aqueous solutions. BET surface area, SEM and TEM images, FT-IR spectrometry, XRD techniques were used for the characterization of the adsorbents. In batch adsorption experiments, parameters affecting the adsorption efficiency such as solution pH, contact time, Th (IV) concentration and temperature were investigated using central composite design (CCD). ANOVA (analysis) analysis at the 95% confidence interval of the model applied for the experimental design and the compatibility of this model with the experimental findings were examined. The relevance of the model for the nanobiocomposite prepared by the 1st method is that the P value is <0.05 and the model F value is 23.77 and 39.45 with the 2nd method, respectively. These results show that the regression for this method is statistically high. The correlation coefficient (R 2), which was 95.69% for the 1st method and 97.36% for the 2nd method, indicates a high coordination between the observed values and the estimated values. According to the CCD results, it has been observed that the main effects of the adsorption process with the materials obtained by the 1st method are in the direction of increasing the concentration, while pH, time and temperature do not have a statistically significant effect. In the adsorption process with the materials obtained by the 2nd method, it was observed that the concentration, time and temperature caused an increasing effect. Langmuir, Freundlich and Dubinin–Radushkevich isotherms were used to determine the adsorption model and the constants related to these isotherms were calculated. In addition, the adsorption process was also investigated in terms of thermodynamics.
Metalized yarns are produced by cutting the films in different thicknesses, metalized with aluminum on one or both sides, in a rectangular form in the desired dimensions and wrapping them on bobbins under a certain tension. Textile products made of these yarns are exposed to repetitive washings like most textile products; metal surfaces of metalized yarns are abraded over time, their bright appearance decreases or disappears. It is undesirable because it affects the lifetime of the final product. In the study, laminated films were produced by the lamination technique using different raw materials to produce metalized yarns with the improved fastness and mechanical properties. Laminated films were subjected to repetitive washings at different temperatures, and the effects of washings on the surface appearance of the films, lamination strength, and optical density properties were examined. As a result of the study, it was determined that repetitive washings reduce the lamination strength, the gloss property is affected by raw material type, the sample type, washing temperature, and the number of washing cycles affect the optical density.
The pre-finishing, finishing, and dyeing processes applied to the fabrics are carried out at high temperatures, in acidic or alkaline environments. Conventional metalized yarns which are produced by metalized yarn companies cannot resist these conditions that change due to raw material type. Metalized parts exfoliate when exposed to these conditions, and shiny appearance disappears completely. Therefore, in order to be a solution for this problem for the products that the use of metalized yarn is required, companies produce fabrics by using metalized yarns that were colored in bobbin form and choose proper application conditions for metalized yarns. However, because this solution increases production time and workmanship, the production costs and the product’s sale price increase correspondingly. The use of metalized yarns with untreated fiber is more advantageous than the method mentioned above for companies in terms of both cost and ease of production process. For this purpose, in this study, the resistance of metalized yarns that were produced by using lamination technique was tested against the chemicals which metalized yarns can be exposed during textile finishing processes, and the appearances of the fabrics were evaluated. Because metalized yarns are commonly used in the production of cotton and polyester fabrics, finishing processes that are applied to cotton and polyester fabrics were applied to metalized fabrics in a textile finishing laboratory. Then post-processing appearances of fabrics were evaluated subjectively.
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