Polymer coatings having high amounts of renewable carbon and self-healing properties are highly sought after in a sustainability perspective. We report here the development of bio-/ CO 2 -derived nonisocyanate polyurethane (NIPU) coatings which are recyclable and healable via three different types of healing mechanisms. These NIPUs contain furan rings in their main chain which after cross-linking with bismaleimides form organogels having a thermo-reversible sol−gel transition and solvent-borne coatings with improved properties. Judicial selection of the bismaleimide cross-linker structure enabled us to produce recyclable and intrinsic healable coatings mediated by heat (thermo-healing), moisture (moisture-healing), and, more interestingly, dry conditions at room temperature (self-healing). The intrinsic moisture-healing property of NIPU-based coatings is unprecedented and is mainly due to the presence of hydroxyl functionalities in the NIPU structure. The uniqueness of these cross-linked biobased NIPU as recyclable coatings having triple healing sites present in their structure gives these materials potential for sustainable and functional applications.

Indazolin-3-ylidenes (indy) are among the most strongly donating N-heterocyclic carbenes, but the structural diversity of their complexes is still limited. Two dimeric palladium­(II) complexes, [PdBr2(indy-5)]2 (2a) and [PdBr2(indy-6)]2 (2b) (indy-5 = 2,3-dihydro-1H-pyrazolo­[1,2-a]­indazolin-3-ylidene, indy-6 = 6,7,8,9-tetrahydropyridazino­[1,2-a]­indazolin-3-ylidene], bearing indazolin-3-ylidene ligands with different sizes of the fused aliphatic ring can be obtained by silver carbene transfer. The reaction of these dimers with pyridine yielded trans-[PdBr2(indy)­(pyridine)] complexes (3a,b), while the poorly soluble monophosphine complexes cis-[PdBr2(indy)­(PPh3)] (4a,b) were obtained by reaction with triphenylphosphine. Ligand substitution of the latter with silver trifluoroacetate afforded cis-[Pd­(O2CCF3)2(indy)­(PPh3)] complexes (5a,b) with improved solubilities, allowing for their detailed characterizations. In the presence of sodium tetrafluoroborate, cationic bis­(phosphine) complexes trans-[PdBr­(PPh3)2]­[BF4] (6a,b) could be obtained. Similarly, cis-[PdBr­(dppe)]­[BF4] (7a,b) and cis-[PdBr­(dppp)]­[BF4] (8a,b) were obtained (dppe = bis­(diphenylphosphino)­ethane; dppp = bis­(diphenylphosphino)­propane) with the respective chelating diphosphines. A preliminary catalytic study revealed that the complexes incorporating monodentate phosphine ligands are good catalysts for the Sonogashira cross-coupling, while moderate to good yields were achieved with all complexes for the hydroamination of carbon–carbon triple bonds.