Concentrated Solar Power (CSP) technology stands out among other renewable energy sources not only because of its ability to address current energy security and environmental challenges but because its energy can be stored for future use. To ensure optimum performance in this system, the heat losses need to be evaluated for better design. This work studies the natural convection in the receiver absorber tube of a CSP plant taking into consideration the influence of neighboring absorbers. A 2-Dimensional model was adopted in this study. Initially, a single absorber tube was considered, it was subjected to heat flux at the top wall, the bottom wall was insulated and a temperature differential was set up at the lateral walls. The dimensionless forms of Navier-Stokes and energy equations were solved using the finite element formulation of COMSOL Multiphysics software. The result obtained for a single absorber tube showed good agreement with existing research works. This validated model was then extended to multiple absorber tubes (two to six absorber tubes). On the basis of the study, there is an observed increase in the intensity and dominance of convective heat transfer with an increase in the number of absorber tubes. This is occasioned by an increase in the average surface temperature as well as average Nusselt number. For the Rayleigh number of 104, 105 and 106, the average Nusselt number increases with the number of absorber tubes by 13.87 %, 6.26 %, and 1.55 %, respectively. This increment suggests effect of thermal interactions among the neighboring absorber tubes
Hydrogen production from the electrolysis of coal slurry is a promising approach under the condition of low voltage (0.8–1.2 V) and medium temperature. However, the rate of hydrogen production is slugged by poor anode kinetics, under an electrochemical condition that results from the collision of the coal particles with the anode surface. This paper reports a novel process that consists of two steps: the oxidation of the coal slurry by ferric ions(III) in a hydrothermal reactor at a temperature of 120–160 °C and the electro-oxidation of ferric ions(II) in the electrochemical cell to produce hydrogen. This technique circumvents the technical issues experienced in the conventional coal slurry electrolysis process by adopting a two-step process consisting of solid–liquid reactions instead of solid–solid reactions. This indirect oxidation process produced a current density of 120 mA/cm2 at room temperature and a voltage of 1 V, which is higher than the values reported in the conventional processes. An investigation of the oxidation mechanism was carried out via scanning electron microscopy, Fourier-transform infrared spectroscopy and elemental analysis. The results obtained showed that the oxidation of coal by ferric ions occurs from the surface to the inner parts of the coal particles in a stepwise manner. It was also revealed that the ferric ions in the media increased the active interfaces both of the coal particles and of the anode electrode. This explains the high hydrogen production rate obtained from this process. This novel discovery can pave the way for the commercialization of coal slurry electrolysis.
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