A technique was developed for preparing a novel material that consists of gold nanoparticles trapped within a fiber of unfolded proteins. These fibers are made in an aqueous solution that contains HAuCl4 and the protein, bovine serum albumin (BSA). By changing the ratio of gold to BSA in solution, two different types of outcomes are observed. At lower gold to BSA ratios (30–120), a purple solution results after heating the mixture at 80 °C for 4 h. At higher gold to BSA ratios (130–170), a clear solution containing purple fibers results after heating the mixture at 80 °C for 4 h. UV–Vis spectroscopy and light scattering techniques show growth in nanocolloid size as gold to BSA ratio rises above 100. Data indicate that, for the higher gold to BSA ratios, the gold is sequestered within the solid material. The material mass, visible by eye, appears to be an aggregation of smaller individual fibers. Scanning electron microscopy and transmission electron microscopy indicate that these fibers are primarily one-dimensional aggregates, which can display some branching, and can be as narrow as 400 nm in size. The likely mechanism for the synthesis of the novel material is discussed.
The non-linearity of general relativity makes it at least difficult if not impossible to view a relativistic cloud of matter as being made up of point-source constituents. Perhaps the most delicate issue to circumnavigate is the inherent lack of the classical notion of superposition. Even if one were to believe that the recent framework developed by the first and the third author in [3] leads to an appropriate interpretation of the phrase "initial data for a point-source", there is prima facie no reason to believe that it lends itself to a principle of superposition. In this paper we propose an extension of said framework which serves as a de-facto superposition of point-sources and which recovers Brill-Lindquist metrics in the limit. We also show that our proposal can be seen as a continuous extension of the classical superposition principle of Newtonian gravity. This paper fits within a larger program of representing relativistic clouds of matter as cumulative effects of pointsources.
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