The heavy-gaugehigh strength steel plates with low yield ratio (YR)

The precipitation behavior of cementite in low carbon steels at various heating rates from 0.3 to 100 K/s has been studied using a high-frequency induction heating apparatus. The materials used in this study were steel platesfor welded structures: 610 and 780 MPa class steel plates with a mixed microstructure of bainite and martensite.Cementite was observed using a carbon extraction replica method and the hardness and toughness were also examined. When heated at the conventional slow rate of 0.3 K/s, relatively large cementite particles with an average diameter of 72 nm precipitated at the lath boundaries, whereas when heated at a rapid rate over 3.0 K/s, cementite precipitated both within the laths and at the lath boundaries, and the cementite was refined down to an average diameter of 54 nm. With such refinement of the cementite, the toughness was improved. On the other hand, the hardness was irrespective of the heating rate and was dependent on the tempering parameter. TEM observations of the cementite precipitation behavior during the rapid heating process revealed that cementite begins to precipitate at the lath boundaries at about 773 K and within the laths at about 873 K. It is concluded that rapid heating especially from 773 to 873 K contributes to the cementite refinement and consequently the improvement in toughness. The effect of alloying elements such as chromium, molybdenum or silicon on the cementite growth during the rapid heating and tempering treatment is also discussed.

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Linepipes installed in permafrost ground or seismic region, where larger strains can be expected by ground movement, are required to have sufficient strain capacity in order to prevent local buckling or girth weld fracture. On the other hand, strain capacity of linepipes usually degreases with increasing strength, and this is one of the reasons for preventing wider use of high-grade linepipe for high strain application. Furthermore, external coating is necessary for corrosion resistance of pipe, but coating heat can cause strain-aged hardening, which results in increased yield strength and Y/T. Therefore, there is a strong demand for developing high strength linepipe for a high strain application with resistance to strain-aged hardening. Extensive studies to develop Grade X100 high strain linepipe have been conducted. One of the key technologies for improving strain capacity is dual-phase microstructural control. Steel plate with the microstructure including bainite and dispersed martensite-austenite constituent (MA) can be obtained by applying accelerated cooling followed by heat treatment online process (HOP). HOP is the induction heating process that enables rapid heating of the steel plates. Variety of microstructural control, such as fine carbide precipitation and MA formation, can be utilized by this newly developed heating process. One of the significant features of the HOP process is to improve resistance to strain-aged hardening. Increase in yield strength by coating can be minimized even for the Grade X100 linepipe. Trial production of X100 high strain linepipe with the size of 36″ OD and 15mm WT was conducted by applying the HOP process. Microstructural characteristics and mechanical properties of developed X100 linepipe are introduced in this paper. In order to evaluate compressive strain capacity of the developed pipe, full-scale pipe bending test was carried out by using the trial X100 high strain linepipe after external coating. Full scale bending test of developed X100 linepipe demonstrated sufficient compressive strain capacity even after external coating.

Extensive studies to develop high strength linepipes with higher deformability have been conducted. One of the key technologies for improving deformability is dual-phase microstructural control. Steel plate with ferrite-bainite microstructure can be obtained by applying Thermo-mechanical controlled processing, TMCP, made up with controlled rolling and accelerated cooling process. Low carbon-boron free steels were used to enable the ferrite formation during cooling after controlled rolling, and the accelerated cooling process with ultimate cooling rate enabled to achieve high strength of up to X120 grade. On-line heating process by induction device was also applied subsequently after accelerated cooling in order to improve Charpy energy of the base material and homogeneity of material properties in the plate. Trial production of X120 high deformability linepipe was also conducted by applying dual-phase microstructural control. Microstructural and mechanical properties of X120 linepipe are introduced in this paper.