Highly dispersed titanium oxide photocatalysts anchored onto transparent plates of porous silica glass were
successfully prepared by metal ion implantation, and their photocatalytic reactivity for the liquid-phase
photocatalytic degradation of an aqueous 2-propanol solution was compared with that in an aqueous TiO2
dispersion. The titanium ions implanted into the porous silica glass are found to be present on the surface
layer as isolated tetrahedral titanium oxide moieties by diffuse reflectance absorption, SIMS, XPS, and XAFS
analyses. The specific photocatalytic reactivity of the anchored catalyst was much higher than that for TiO2
powder, which may be attributed to the tetrahedrally coordinated titanium oxide moieties. Metal ion implantation
is one of the novel and useful techniques to prepare highly efficient photocatalysts on glass plates.
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