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A study of PCB concentrations and fluxes in lake sediments was conducted to test the “global fractionation” hypothesis that deposition of semivolatile organics will decline while more volatile congeners will be enriched in polar regions. Sediment cores were collected from 11 remote lakes in Canada ranging from 49° N to 82° N and were dated using excess 210Pb and 137Cs. Sediment extracts were analyzed for up to 90 PCB congeners by capillary GC-ECD with confirmation by GC/high-resolution MS. Total PCB (∑PCB) concentrations in surface slices ranged from 2.4 to 39 ng g-1 (dry wt) and showed no latitudinal trend. Fluxes (ng m-2 yr-1) and inventories of ∑PCB as well as total tetra- to octachlorobiphenyls declined with increasing north latitude while those for di/trichlorobiphenyls showed no latitudinal trend. The proportion of di/trichloro congeners of ∑PCB also increased significantly with latitude, while total octachlorobiphenyls declined. Maximum ∑PCB concentrations were observed in subsurface slices dating to the 1960−1970s in most lakes except those in the high Arctic, where maxima were generally in surface slices. The onset of elevated ∑PCB deposition was delayed in the high Arctic (1950−1960s) relative to the midlatitude and sub-Arctic lakes (1930−1940s). The high proportions of lower chlorinated congeners and the delayed appearance of PCBs are consistent with predictions of the global fractionation model.

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The variation in levels of polychlorinated biphenyls (sigma PCBs), chlorobenzenes and chlorinated pesticides was studied in burbot (Lota lota) from eight remote locations along a northwesterly transect from northwestern Ontario to the Mackenzie River delta in Canada. Significant declines in concentrations of PCB congeners, DDT isomers (sigma DDT), lindane, dieldrin, and mirex in burbot liver were found with increasing north latitude. Mean sigma PCB concentrations ranged from 1,290 ng/g (lipid wt) at Lake 625, a remote lake in northwestern Ontario, to 301 ng/g in samples from the Mackenzie River at Arctic Red River, N.W.T. No significant differences in mean concentrations of toxaphene, alpha-HCH, tri- and tetrachlorobiphenyls were observed between southern and northern sampling sites. Toxaphene was the predominant organochlorine residue in northern fish samples averaging 1,400 ng/g (lipid wt) at the three most northerly sites and 1,723 ng/g at Lake 625. Airborne contamination was the only likely source of organochlorines for most of the locations surveyed. The results were consistent with the hypothesis that inputs of semi-volatile organochlorines to northern aquatic ecosystems decrease with increasing north latitude and distance from North American sources.