The physical and degradation properties of polylactic (PLA)/thermoplastic starch (TPS) blends after TPS modification with citric acid (CA) were investigated. The interfacial adhesion between the PLA and TPS was expected to improve, thus enhancing the physical properties of the PLA/TPS blends. The tensile strength and Young's modulus for PLA/TPS blends at (60/40) and (40/60) blends ratio were found to increase after modification with CA. On the other hand, the elongation at break of the (60/40) blend decreased, while elongation at break of the (40/60) blend increased. Meanwhile, an additional peak at 1721 cm -1 was detected by the FTIR spectroscopic analysis, which indicated that the TPS had chemically interacted with the CA. The biodegradability properties of PLA/TPS blends were also improved after treatment with CA. The deterioration of PLA/TPS blends was attributed to the incorporation of CA; O2 from the soil was attracted to the PLA/TPS blends, thus speeding up the degradation process of the blends.
Abstract. Alterations on the land surfaces, which are attributed by human activities, especially in cities, cause many implications to the ecosystem. The increase of buildings in cities is reflecting the growth of human activities resulted in a significant temperature increase and warmer pattern in the urban area than the surrounding countryside. The phenomenon defined as urban heat island. This study investigates the application and efficiency of the green roof as an approach to mitigate urban heat island and reducing indoor temperature in a building. Two types of roof models, which consist of vegetative roof and non-vegetative roof, were built to investigate the efficiency of vegetated roof in reducing indoor temperature compared to the non-vegetated roof. The outdoor and indoor temperature and humidity of each roof model were monitored by using RH520 Thermo Hygrometer. The data was collected for three times in a week for 9 weeks at 9:00am to 5:00pm. It was found that the indoor average temperature data for vegetative roof could be reduced 2.4 C from the outdoor average temperature and 0.8 C for non-vegetative roof. The difference of temperature reduction for vegetative roof was greater than the nonvegetative roof, thus indicate that green roof was highly efficient in reducing indoor temperature and mitigate urban heat island impact.
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