We report a new nickel‐iron alloy nanoparticle‐decorated LaSrFe0.75Ni0.25O4 K2NiF4‐type oxide with Ruddlesden‐Popper structure (RP‐LSFN), which performed as a high‐performance sulfur‐resistant anode prepared by using an infiltration method for solid oxide fuel cells (SOFCs) with LaSrFeNiO6‐δ double perovskite (DP‐LSFN) as the precursor. A reduction converts the DP‐LSFN phase into mixed phases containing the RP‐LSFN and FeNi3 nanoparticles. The morphology, thermal expansion behavior, sulfur tolerance, and electrochemical activity for hydrogen oxidation of this FeNi3 nanoparticle‐decorated, RP‐LSFN‐infiltrated anode are investigated. An electrolyte‐supported SOFC with this infiltrated anode generates a high power output of 541 mW cm−2 at 800 °C operated with 1000 ppm H2S−H2 as the fuel, which compares favorably to that with pure H2 fuel. A single cell with this anode demonstrates favorable stability at 800 °C during 90, 40, and 20 h operation with H2 containing 100, 200, and 1000 ppm H2S, respectively.
An increasing number of personal electronic handheld devices (e.g., SmartPhone, netbook, MID and etc.), which make up the personal pervasive computing environments, are playing an important role in our daily lives. Data storage and sharing is difficult for these devices due to the data inflation and the natural limitations of mobile devices, such as the limited storage space and the limited computing capability. Since the emerging cloud storage solutions can provide reliable and unlimited storage, they satisfy to the requirement of pervasive computing very well. Thus we designed a new cloud storage platform which includes a series of shadow storage services to address these new data management challenges in pervasive computing environments, which called as "SmartBox". In SmartBox, each device is associated its shadow storage with a unique account, and the shadow storage acts as backup center as well as personal repository when the device is connected. To facilitate file navigation, all datasets in shadow storage are organized based on file attributes which support the users to seek files by semantic queries. We implemented a prototype of SmartBox focusing on pervasive environments being made up of Internet accessible devices. Experimental results with the deployments confirm the efficacy of shadow storage services in SmartBox.
Because of the bottleneck of disk I/O, the distributed file system based on disk is limited in the performance on data throughput and latency. It is a big challenge for such a system to meet the high performance requirement of the massive small-file storage.Cache has been widely used in storage system to improve the data access performance. In order to support the storage of massive small files, we have integrated memcached into our distributed file system to optimize the storage of massive small files. However eviction problem arose from LRU replacement algorithm in memcached. It means that the non-stale objects might be replaced due to large short-lived objects. Therefore, we proposed Prioritized Cache (PC) and Prioritized Cache Management (PCM) to solve the problem. The cache of memcached is reorganized and classified into permanent cache and temporary cache. Furthermore, in order to alleviate side effects on hit rate in sequential access, temporary cache is partitioned into different parts with different priorities and managed according to the priorities. We have implemented and evaluated the integrated prototype system. The experimental results show that the improved distributed file system with distributed object cache can deliver high performance on smallfile storage. Compared with the original system, the read of small files increased by a factor of 2.65 8.05, without write performance degradation.
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