Due to the increasing demand on developing good insulation, several researchers have performed experimental studies to prove the effectiveness and capabilities of transformer oil. This is done by suspending nanosized solid particles in the oil (nanofluid) for transformer applications. In brief, this paper presents a compilation of research studies which is divided into three parts. Part I discuss the preparation of the nanofluid which involves different types of nanomaterials, the optimal amount of concentrations, and applicable synthesisation methods for producing stably suspended nanofluids. In Part II, the nanofluid’s performances including the electrical breakdown voltages, impulse tests, and thermal and dielectric behaviour are reviewed in depth and compared. Part III emphasizes the limitation of nanofluids. Most researchers have agreed that appropriate concentrations of nanomaterials and the preparation method for nanofluids mainly affect the performance of nanofluids especially in terms of electrical properties. Meanwhile, types of nanomaterials and base oil also play a vital role in producing nanofluids as a better alternative transformer oil. However, among a few researchers, there are concerns regarding the issue of agglomeration and inconsistencies of findings that need to be resolved. Therefore, a few aspects must be taken into consideration to produce the next generation of high heat dissipation insulation.
This paper intends to prepare a nanofluid sample by suspending Multi-walled Carbon Nanotubes (MWCNTs) at 0.005g/L concentration and analyze the behavior of electrical and dielectric properties based on the International Electrotechnical Commision test method. In order to validate the effectiveness of MWCNT nanofluid, alternating current breakdown voltage (BDV), negative polarity lightning impulse (LI), dielectric permittivity, dissipation factor (DF), DC resistivity and Raman structural measurement are executed accordingly. In the following, an analysis of the statistical distribution using the two-parameter Weibull distribution law of BDV and LI are evaluated at four experimental conditions to predict the probability of breakdown occurring at different percentages. Based on the observation, the MWCNT filler has a substantial effect in improving the BDV and LI characteristics of disposed mineral oil. The permittivity, DF and resistivity performance of MWCNT nanofluid from 25 °C to 90 °C also produces comparable and reliable performance as a fresh transformer oil. As for Raman structure, the revolution of transformer oil by doping MWCNT does not disrupt the original chemical structure of mineral oil. Hence, this study proves the improvement of the electrical and the behavior of dielectric properties and chemical structure of nanofluid, providing a huge contribution towards the development of insulating materials for transformer application.
In this paper, the electrical, dielectric, Raman and small angle X-ray scattering (SAXS) structure behavior of disposed transformer oil in the presence of multi-walled carbon nanotube (MWCNT) were systematically tested to verify their versatility for preparing better alternative transformer oil in future. MWCNT nanofluids are prepared using a two-step method with concentrations ranging from 0.00 to 0.02 g/L. The test results reveal that 0.005 g/L concentration possesses the most optimum performance based on the electrical (AC breakdown and lightning impulse) and dielectric (permittivity, dissipation factor and resistivity) behavior. According to the trend of AC breakdown strength and lightning impulse pattern, there were 212.58% and 40.01% enhancement indicated for 0.005 g/L concentration compared to the disposed transformer oil. The presence of MWCNT also yielding to the decrement of dissipation factor, increased on permittivity and resistivity behavior of disposed transformer oil which reflected to the performance of electrical properties. Furthermore, it is found that these features correlated to the structural properties as systematically verify by Raman and SAXS analysis study.
This paper studies the electrical efficiency of carbon nanotubes (CNT) with nanosized diameter inserted into palm-based oil at various concentrations (0, 0.0125, 0.025, 0.0375, 0.05, 0.125, 0.25 and 0.5 g/L). Dispersion methods, including sonication and drying process were systematically applied for producing stable CNT nanofluids. Several parameters such as electrical properties (AC breakdown voltage) and dielectric properties (dissipation factor, relative permittivity and resistivity) were measured accordingly based on IEC 60156 and IEC 60247 international standards. The test results reveal that the higher concentration of CNTs dispersed in palm oil, the lower AC breakdown voltages produced. At 0.5 g/L concentration, the average of 50 breakdown was 22.30 kV, which is 72.33% decrement compared to palm oil without any nanofiller. Besides, the permittivity and resistivity of CNT nanofluids decrease as concentrations increased, while dissipation factor increases along with CNT concentrations. In order to further support this indication, Raman analysis is measured to relate the behavior of AC breakdown voltages and chemical structure of CNT nanofluids. Based on the Raman spectra at 2800-3200 cm-1 region, it is shown that the value of total unsaturated fatty acid and total fatty acid decreased as concentrations of CNT increased. This occurrence directly influences the degradation performance of AC breakdown voltages.
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