Application of alternative “click” strategies (metal-free photoclick and one-pot click) to cymantrene and ferrocene derivatives yielded novel metal-containing conjugates.
Over several years, our research team has contributed to ligand design for metal-catalyzed stereoselective transformations. This has been achieved with the synthesis and application to organic transformations of interest of an array of structurally diverse P-containing ligands. These range from highly modular enantiopure phosphine–phosphite ligands to supramolecularly regulated enantioselective phosphorus-based catalysts. Our research in supramolecular interactions has also led to the discovery of an unprecedented halogen-bonded rhodium-catalyst.
Nickel(0) complexes derived from electron-rich triarylphosphines as efficient catalysts for intramolecular [4+4]-cycloadditions of an array of structurally diverse bis-dienes.
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