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The relaxor behavior of lanthanum modified lead zirconate titanate (PLZT) ferroelectric ceramics, for a La/Zr/Ti ratio of x/60/40, has been analyzed. An approximation to the dynamical behavior of the polar nano-regions (PNRs) has been discussed, taking into account a relaxation model, which considers a distribution function for the relaxation times. A good agreement between theoretical and experimental results was obtained. The behaviors of the mean relaxation time and its standard deviation with temperature were discussed, considering the correlation between the polar nano-regions and the freezing temperature. The temperature dependence of the polarization showed an anomalous behavior around a temperature, which was associated with the freezing temperature, according to the proposed model in the present work.

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The stabilization of δ-phase of poly(vinylidene fluoride) PVDF in a 14 µm-thickness ferroelectric membrane is achieved by a simple route based on the use of a dimethylformamide (DMF)/acetone solvent, in which the application of external electric field is not required. X-ray diffraction and calorimetric experiments on heating reveal that, at 154 °C, the original mixture between ferroelectric δ-phase and paraelectric α-phase transits to a system with only this latter phase in the crystalline fraction. A gradual and slight increment of amorphous fraction up to the melting at 161 °C is also observed. The existence of δ-phase is corroborated by the occurrence of a broad maximum around 154 °C in dielectric permittivity measurements, as well as the hysteresis loops observed at room temperature. These results suggest a wide thermal window for a stable δ-phase, between room temperature and 154 °C, a subsequent transition into α-phase and the corresponding melting at 161 °C. The broad dielectric maximum observed around 154 °C in dielectric and calorimetric measurements, can be associated with a diffuse ferroelectric-paraelectric transition.