This study performed with soybean (Glycine max L.), one of the most important crops for human and animal nutrition, demonstrates that changes in the leaf surface structure can increase the adhesion of applied droplets, even on superhydrophobic leaves, to reduce undesirable soil contamination by roll-off of agrochemical formulations from the plant surfaces. The wettability and morphology of soybean (Glycine max L.) leaf surfaces before and after treatment with six different surfactants (Agnique® SBO10 and five variations of nonionic surfactants) have been investigated. The leaf surface structures show a hierarchical organization, built up by convex epidermal cells (microstructure) and superimposed epicuticular platelet-shaped wax crystals (micro- to nanostructure). Chemical analysis of the epicuticular wax showed that 1-triacontanol (C30H61OH) is the main wax component of the soybean leaf surfaces. A water contact angle (CA) of 162.4° (σ = 3.6°) and tilting angle (TA) of 20.9° (σ = 10.0°) were found. Adherence of pure water droplets on the superhydrophobic leaves is supported by the hydrophilic hairs on the leaves. Agnique® SBO10 and the nonionic surfactant XP ED 75 increased the droplet adhesion and caused an increase of the TA from 20.9° to 85° and 90°, respectively. Scanning electron microscopy showed that surfactants with a hydrophilic–lipophilic balance value below 10 caused a size reduction of the epicuticular wax structures and a change from Cassie–Baxter wetting to an intermediate wetting regime with an increase of droplet adhesion.
Garnet films of high Faraday rotation are applied as magneto-optical sensors to visualize the spatial distribution of magnetic fields. Using specific orientations, the induced anisotropy can generate an easy plane of magnetization which is inclined with respect to the film plane. If the magnetization lies in this plane a very high sensitivity can be achieved. The dependence of the geometrical orientation of the easy plane on the growth direction is calculated and the sensitivity and dynamic range are derived. Experimental results of a [112] oriented garnet film are in good agreement with calculations.
Rare-earth iron garnet films with in-plane magnetic anisotropy grown on [111]-oriented substrates are promising for the visualization of magnetic leakage fields in nondestructive evaluation. Such magneto-optical films have to be specifically engineered, and we give an example of this technology. To assess the validity and accuracy of finite-element calculations of a magnetization assembly combined with the physical modeling of the image formation, comparisons between calculated and experimentally obtained magneto-optical images of metal-loss defects have been made. A convincing quantitative agreement is demonstrated. It is shown that both physical and computer modeling techniques allow for a predictive engineering design of the prospective applications and provide greater insight into the method.
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