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The pressure-induced structural phase transition in the intermediate-valence compound CeNi has been investigated by X-ray and neutron powder diffraction techniques. For the first time it is shown that the structure of the pressure-induced CeNi phase (phases) can be described in terms of the P nma space group. Equations of state for CeNi on both sides of the phase transition are derived and an approximate P − T phase diagram is suggested for P < 8 GPa and T < 300 K. The observed Cmcm → P nma structural transition is analyzed using density functional theory (DFT) calculations, which successfully reproduce the ground state volume, the phase transition pressure, and the volume collapse associated with the phase transition.

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