The triple point of water serves to define the kelvin, the unit of thermodynamic temperature, in the International System of Units (SI). Furthermore, it is the most important fixed point of the International Temperature Scale of 1990 (ITS-90). Any uncertainty in the realization of the triple point of water contributes directly to the measurement uncertainty over the wide temperature range from 13.8033 K to 1234.93 K.The Consultative Committee for Thermometry (CCT) decided at its 21st meeting in 2001 to carry out a comparison of water triple point cells and charged the BIPM with its organization.Water triple point cells from 20 national metrology institutes were carried to the BIPM and were compared with highest accuracy with two reference cells. The small day-to-day changes of the reference cells were determined by a least-squares technique. Prior to the measurements at the BIPM, the transfer cells were compared with the corresponding national references and therefore also allow comparison of the national references of the water triple point.This report presents the results of this comparison and gives detailed information about the measurements made at the BIPM and in the participating laboratories. It was found that the transfer cells show a standard deviation of 50 µK; the difference between the extremes is 160 µK. The same spread is observed between the national references.The most important result of this work is that a correlation between the isotopic composition of the cell water and the triple point temperature was observed. To reduce the spread between different realizations, it is therefore proposed that the definition of the kelvin should refer to water of a specified isotopic composition.The CCT recommended to the International Committee of Weights and Measures (CIPM) to clarify the definition of the kelvin in the SI brochure by explicitly referring to water with the isotopic composition of Vienna Standard Mean Ocean Water (VSMOW). The CIPM accepted this recommendation and the next edition of the SI brochure will include this specification.Main text. To reach the main text of this paper, click on Final Report. Note that this text is that which appears in Appendix B of the BIPM key comparison database kcdb.bipm.org/.The final report has been peer-reviewed and approved for publication by the CCT, according to the provisions of the CIPM Mutual Recognition Arrangement (MRA).
From 2002 to 2004 the Consultative Committee for Thermometry (CCT) carried out a Key Comparison (KC) of water triple point cells (CCT-K7). In 2005 the Regional Metrology Organization (RMO) EURAMET decided to initiate an additional KC of water triple point cells, EUROMET.T-K7, to extend the metrological equivalence to a larger number of national metrology institutes (NMIs) from the EURAMET region.The EUROMET.T-K7 comparison was carried out in 2006–2008 with the coordination of VSL and the participation of 24 EUROMET NMIs, 9 of them having participated in CCT-K7 as well (8 out of 9 used the same transfer cell they had used in CCT-K7).This report presents the results of this comparison, provides detailed information of the measurements performed by all participating laboratories and links the comparison results to the CCT-K7 comparison.Main text. To reach the main text of this paper, click on Final Report. Note that this text is that which appears in Appendix B of the BIPM key comparison database kcdb.bipm.org/.The final report has been peer-reviewed and approved for publication by the CCT, according to the provisions of the CIPM Mutual Recognition Arrangement (MRA).
Distributed temperature sensing (DTS) allows for simultaneous measurement at many remote locations along an optical fiber probe and is a valuable tool in a broad range of applications, such as downhole oil production, dike structural monitoring or fire protection. The specific requirements on spatial, temporal and temperature resolution and on absolute measurement uncertainty vary with the applications. We investigate the spatio-temporal noise and drift properties of two exemplary Raman backscatter DTS systems and discuss the effect of spatial and temporal data averaging. An Allan deviation analysis provides insight into the optimal degree of averaging for a given distance range along the fiber probe. A temperature calibration procedure is employed to retrieve the temperature sensitivity of the DTS system and to compensate for the systematic spatial slope of recorded DTS temperature measurement traces. In response to small temperature steps of a thermally homogeneous and stable water bath environment, we observe a temperature resolution of approximately 0.05 °C at a chosen 1000 m sampling distance along the fiber probe.
The EUROMET.T-K4 comparison is the regional extension of CCT-K4, an intercomparison of the realizations of the freezing points of Al (660.323 • C) and .78 • C). The intercomparison was organized in four loops. Long-stem standard platinum resistance thermometers (SPRTs) were used as traveling standards: 25 thermometers to be used only at the Al freezing point and two high-temperature standard platinum resistance thermometers (HTSPRTs) to be used only at the Ag freezing point in each loop. Parallel to the measurements with thermometers, the pilots and sub-pilots organized an internal intercomparison using an Ag fixed-point cell. Most HTSPRTs showed a strong drift which is mainly due to mechanical stress and poisoning of the sensor by impurities. This drift can be partially compensated by a correction based on Matthiessen's rule. An evaluation of the data taking into account both HTSPRTs in each loop, the linkage of the sub-pilots by measurements at the Ag freezing point, and a possible compensation according to Matthiessens's rule, allows calculation of the results of the participants' measurements at the Ag freezing point. The results of the participating laboratories are summarized, and proposals for key comparison reference values and linking of the results to CCT-K3 and CCT-K4 are presented.
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