Homopo}ycondensation of l-halogenopropane-2-thiones was studied; the polymers obtained were strttcturally characterized by ESR. UV, and IR spectroscopy, elemental analysis, and electrochemical methods. Their molecular masses, dark conductivities, and photoconductivities were determined The capability fi~r film formation on variotLs substrates was investigated. These polymers were found to be new organic metals (Hal = I). semiconductors (Hal = CI and Br). and photoconductors (Hal = CI. Br)

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The article considers the possibility of reduction of anthropogenic impact on ecosystems of various levels of waste of mining complex by their largetonnage direct using in the construction industry. The methods of utilization of waste crushed production modified with natural zeolites and stabilizing additive in the composition of soil concrete are studied. The chemical and phase compositions of the inital mineral raw materials and soil concrete based on them are studied by a complex of modern methods. Optimal mass fractions of clinoptilolite rock (5–15 wt. %) and a polymeric stabilizing additive (1 wt. %) allowing to obtain composites with a maximum strength grade of 100 (М 100) are established. The increase of strength characteristics of soil concrete modified with zeolite-containing rock is associated with an increase of their density by the presence of crystalline calcium and magnesium silicates in the structure as well as the filling of the interparticle space with mineral and polymer additives.

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The technology of obtaining solid electrolytes by mechanochemical method with subsequent cold pressing from inexpensive common clinoptilolite rocks and ionic salts – sodium and ammonium hydrophosphates at varying ratios of the initial components and the duration of mechanical activation is presented. Their physical and transport properties, namely, true density, hygroscopic humidity, specific surface according to Tovarov, volumetric electrical conductivity were found. Promising samples for further research were created, recommended for use as solid electrolytes.