Co-ordinationChemistry of Sulphines. Part 3 . ' Oxidative Addition of the Carbon-Chlorine Bond of (€)-Chloro(ary1thio)-sulphine, (€)-(RS)CICSO, to Tetrakis(triphenylphosphine)platinum(o) and of a Carbon-Sulphur Bond in [ Pto( PPh&(( RS)2CSO)] by an Intramolecular Process. X-Ray Crystal and Molecular Structure of cis-(E)-[PtIl( PhS)(PhSCSO)-(PPh3)210C6H6
Die nksul?n‐Pt‐Komplexe (Ia) und (Ib) unterwerfen sich in Lösung einer vollständigen intramolekularen oxidativen Addition einer der C‐S‐Bindungen an das Pt(0) unter Bildung eines Gleichgewichtsgemisches der cis‐(E)‐und cis‐(Z)‐Produkte (IIa) und (IIIa) bzw. (IIb) und (IIIb).
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