A central problem in the numerical treatment of melting and resolidification, as well as alloying processes at metal surfaces, is the coupling of the physical phenomena. Among these phenomena, Marangoni convection, conjugated heat transfer, species transport and free-surface deformation occur simultaneously. The involved transport mechanisms take place at different time scales, which enables the decoupling of the governing equations in the solution process. This decoupling procedure has been proven to be capable of computation of metal-surface remelting and alloying processes. In this article, scaling analysis is presented to determine both the time scales and characteristic velocities. Using this information, two-dimensional transient calculations of velocities, temperatures, and species concentration in both liquid and solid phases have been carried out. These theoretical results have been compared with experiments utilizing the high-speed scan deflection technique in electron-beam (EB) surface remelting and alloying of a Ck45 specimen (AISI 1045) with chromium. It was shown that the shape of the resolidified surface is determined by the fluctuation of the vapor pressure. This fluctuation is due to temperature oscillations induced by the transient behavior of the electron beam.
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