The IR, 'H and 13C NMR spectra of six esters of 1-aryl-4-methyl-3and 5-pyrazolecarbogylic acids are reported. On the bask of their spectra the 3-or 5-position of the substibent in such structural isomeric p& can be established Without recourse to the spectrum of the other member of the pair. The spectral data also give information on the conformation, which depends on the relative position and size of the heten, ring substituents.
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