Synthesis of rod‐shaped nanocrystalline lanthanum phosphate with an average length of 40 nm even after calcination at 400 °C has been realized through a room‐temperature aqueous sol–gel process. The sol is characterized by particle‐size, zeta‐potential, and viscosity measurements. Gelation of the sol is induced by ammonia. The lanthanum phosphate phase‐formation process is followed by thermal, Fourier‐transform IR, and X‐ray diffraction analysis. Transmission electron microscopy shows that the sol and gel particles have a rod‐shaped morphology and comparable particle sizes. Using the Scherrer equation a crystallite size of 11 nm is obtained for the gel powder calcined at 400 °C and Brunauer–Emmett–Teller (BET) nitrogen‐adsorption analysis showed a high specific surface area of 100 m2 g–1. Ammonia temperature‐programmed desorption measurements show that the density of Lewis acid sites is four times higher than ever reported in the case of lanthanum phosphates. The catalytic activity of the above sample is demonstrated by using it as a Lewis‐acid catalyst in an acetal‐formation reaction with a very good yield of 85 %. The sol is used to develop nanocoatings on a glass surface and the morphology of the coatings is investigated using atomic force microscopy and scanning electron microscopy. The microstructure of the coating confirmed the rod‐shaped nature of the sol particles. The coating was uniform with a thickness of about 55 nm.

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Raman measurements applied on freshly tattooed porcine skin ex vivo showed a possibility of obtaining the ink pigment related information in the skin. Based on these results, confocal Raman microscopy was used to identify the tattoo ink pigments of different colors in multicolored tattooed human skin in vivo. The Raman signatures of tattoo ink pigments were unique. Therefore, it could be shown that the applied method is successful for the identification of the tattoo ink pigments in human skin in vivo down to depths of approx. 50 μm, which is sufficient to screen the entire epidermis and the top of the papillary dermis area on the forearm and leg skin sites. Additional application of the optical clearing technique in vivo by topical application of glycerol, combined with tape stripping removal of the uppermost stratum corneum layers and defatting allows the extension of depths of investigation in tattooed skin down to approx. 400 μm, i.e. to cover the entire papillary dermis and a large part of the reticular dermis. Thus, the tattoo ink pigments were identified in vivo and depth-dependently in human tattooed skin confirming their presence in the papillary and reticular dermis. The proposed non-invasive in vivo Raman screening combined with optical clearing for identifying the tattoo pigments in the dermis can be an important task preceding a laser-based tattoo removal procedure and for determining the optimal laser parameters.

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