This paper considers a possibility to obtain high-quality butt junctions of bimetallic sheets from steel clad with a layer of titanium, with the use of barrier layers. The task that was tackled related to preventing the formation of Ti-Fe intermetallic phases (IMPs) between the steel and titanium layer. The barrier layers (height ~0.5 mm) of vanadium and copper alloys were surfaced by arc techniques while minimizing the level of thermal influence on the base metal. To this end, plasma surfacing with a current-driving wire and pulsed MAG surfacing were used. The obtained samples were examined by methods of metallography, X-ray spectral microanalysis, durometric analysis. It has been established that when a layer of vanadium is plated on the surface of titanium, a defect-free structure of variable composition (53.87–65.67) wt % Ti with (33.93–45.54) wt % V is formed without IMPs. The subsequent surfacing of steel on a layer of vanadium leads to the formation of eutectics (hardness up to 5,523 MPa) in the fusion zone, as well as to the evolution of cracks. To prevent the formation of IMPs, a layer of bronze CuBe2 was deposited on the surface of vanadium. The formed layer contributed to the formation of a grid of hot cracks. In the titanium-vanadium-copper transition zones (0.1–0.2 mm wide), a fragile phase was observed. To eliminate this drawback, the bronze CuBe2 was replaced with bronze CuSi3Mn1; a defect-free junction was obtained. When using a barrier layer with CuSi3Mn1, a defect-free junction was obtained (10–30 % Ti; 18–50 % Fe; 5–25 % Cu). The study reported here makes it possible to recommend CuSi3Mn1 as a barrier layer for welding bimetallic sheets "steel-titanium". One of the applications of the research results could be welding of longitudinally welded pipes of main oil and gas pipelines formed from bimetallic sheets of steel clad with titanium.

This paper reports a study into the regularities of interphase interaction, features in the formation of intermetallic phases (IMPs), and defects when surfacing steel on titanium in four ways: P-MAG, CMT, plasma surfacing by an indirect arc with conductive wire, and PAW. A general tendency has been established in the IMP occurrence when surfacing steel on titanium by all the considered methods. It was determined that the plasma surfacing technique involving an indirect arc with conductive wire is less critical as regards the IMP formation. That makes it possible to obtain an intermetallic layer of the minimum thickness (25...54 μm) in combination with the best quality in the formation of surfaced metal beads. Further minimization of the size of this layer is complicated by a critical decrease in the heat input into the metal, which gives rise to the capability of the surfaced metal to be collected in separate droplets. The formation of TiFe2, TiFe, and the α-Fe phase enriched with titanium in different percentage compositions has been observed in the transition zone of steel surfacing on titanium under different techniques and modes of surfacing. The study has shown the possibility of formation, in addition to the phases of TiFe2 and TiFe, the Ti2Fe phase at low heat input. The technique of plasma surfacing by an indirect arc with conductive wire minimizes the thermal effect on the base metal. When it is used at the border of the transition of the layer of steel surfaced on titanium, the phase composition and structure of the layers in some cases approach the composition and structure of the transition zone of the original bimetallic sheet "titanium-steel" manufactured by rolling. A layer up to 5 μm thick is formed from the β phase with an iron concentration of 44.65 % by weight and an intermetallic layer up to 0.2...0.4 μm thick, close in composition to the TiFe phase. The next step in minimizing the IMP formation might involve the introduction of a barrier layer between titanium and steel.

The object of this study is structural formation during the surfacing of steel (iron) on titanium with plasma-sprayed coatings to obtain a butt connection of titanium-steel bimetallic plates. The task to be solved was to devise a technology for applying a barrier layer between titanium and steel to obtain a defect-free butt joint of the edges of bimetallic sheets of carbon steel, clad with a layer of titanium, under conditions of arc or plasma surfacing of carbon steel on titanium. The application of the barrier layer was carried out by plasma spraying of steel wire or iron powder. In this case, a coating with a thickness of 150...750 μm was applied on Grade2 titanium, on which 1–2 mm thick layers of materials similar to the sprayed ones were deposited by arc and plasma deposition. It was established that during spraying with subsequent surfacing of steel wire or iron powder, the main technological factors for eliminating cracks in the resulting compound are the thickness of the sprayed coating and the amount of linear surfacing energy. The thickness of the sprayed coating was selected (at least 400...600 microns) followed by plasma surfacing of ER70S-6 steel wire with a diameter of 1.0 mm or CNPC-Fe200 iron powder with unit energy up to ~200...250 J/mm. A defect-free transition layer from titanium to steel was obtained. It is a continuous layer with a thickness of 50–60 microns, consisting of intermetalides FeTi and FeTi2, as well as a β-phase titanium with an enhanced iron content, which retains certain ductility without cracks and other defects. With the help of the devised approach for connecting titanium-steel bimetallic edges, it is planned to manufacture seam bimetallic pipes for main pipelines to transport oil and gas raw materials extracted from wells.

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