Effect of content of synthetic aluminosilicates in medium-density polyethylene on the fire hazard characteristics and mechanical properties of compositions is investigated. It has been shown that during decomposition of the filler with the release of water, its effectiveness depends not only on the endothermic effect of decomposition and the content of dehydration products, but also on the correspondence of temperature of the dehydration of the filler and the temperature of intensive decomposition of the polymer. Regardless of the type of fillers, an increase in their content in polymer composite material helps to reduce combustibility. It has been shown that compositions based on epoxy oligomers or medium-density polyethylene and synthetic zeolite have properties of self-extinguish and fairly high physical and mechanical characteristics. It is shown that epoxy polymer composite material with the content of inorganic fillers 40-70 wt.% can be used for sealing building structures and other products operating at elevated temperatures, as well as in a mode where the fire resistance and heat resistance of the sealing compound are decisive. A number of efficiency of flame-suppressing of fillers is presented. Formulations of compositions based on epoxy oligomers or medium-density polyethylene whith synthetic zeolite having an optimal ratio of fire hazard and mechanical properties and not having toxic or carcinogenic effects when heated are recommended.
The choice of silicone materials for manufacturing of technical means of rehabilitation of high functionality has been validated. Comparison of physical mechanical properties of domestically produced high-temperature silicones with the materials produced by leading European companies has been carried out. The use of the particular brand of domestically produced high-temperature silicones is recommended according to strength and elastic properties for different groups of products. Efficiency of use of high-temperature silicones in manufacturing of components for prostheses, including bionic ones, has been specified.
The article considers methods of manufacturing non-toxic films of a given color that meet technological requirements. The problem of reducing the shrinkage of the colored polymer in the casting mould during cooling and maintaining its technical characteristics is experimentally solved. To this end, the influence of the nature of pigments on the degree of polymer coloring is studied, and ways to improve the quality of color are investigated. The object of the study was selected pigment concentrate based on high pressure polyethylene brand 15803-003. The pigment has chosen technical carbon grades N220, P803. Surfactants were modifying additives. Tests of samples to determine the light fastness of dye, migration resistance, the number of agglomerates of pigments, toughness and strength, physical and mechanical properties showed that the most effective additive to improve the coloring properties of soot pigment brand N220 and improve the appearance of finished products introduced into the superconcentrate calcium stearate, which at the stage of mixing in the extruder acts as a surfactant and prevents the adhesion of the pigment and the formation of agglomerates in the polymer melt.
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