Quantification of ice rafted debris (IRD) abundances in deep‐sea records is often used as a key proxy for identifying links between ice sheet instability and the oceanic overturning circulation. There currently exist multiple methods to determine IRD content in deep‐sea sediment cores. The preference for a given method is often determined by the accessibility to core material and destructive nature of some methods. While many studies have discussed the caveats between linking IRD to ice sheet dynamics, the uncertainties relating to the methodological approaches are often not considered in the interpretation or comparisons between different IRD datasets, particularly in the Antarctic. To address this, we compare three independent methodologies of obtaining IRD abundances and also discuss how different approaches will affect determinations of mass accumulation rates (MARs). The three methodologies we examine include: counting clasts >2 mm in x‐radiographs; the sieved weight percentage of the medium‐to‐coarse sand fraction (250 μm–2 mm); and volumetric estimates of the >125 μm sand fraction using laser diffraction particle size analysis. The x‐radiograph and sieve methods produced comparable results, while the laser particle size analysis, although showing comparable long‐term signals at most locations, in general has lower correlation to the other two methods and therefore a higher potential to obtain a noisy signal. We discuss the caveats associated with all methods, and emphasize that a combination of multiple methods should ideally be employed when assessing if a core is suitable for IRD study, and if sand or gravel fractions are accurately reflecting contents of IRD.

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<p>This thesis investigates glacimarine sedimentation processes operating on the continental margin of the western Ross Sea during the Pleistocene (˜2.5 Ma). This time period is characterised by a major global cooling step at ˜0.8 Ma, although several proposed episodes of major marine-based Antarctic Ice Sheet (AIS) retreat in warm interglacial periods are inferred to have occurred after this time. Constraining the timing and magnitude of past marine-based AIS retreat events in the Ross Sea through this time will improve our understanding of the forcing mechanisms and thresholds that drive marine-based ice sheet retreat. Identifying such mechanisms and thresholds is crucial for assisting predictive models of potential ice sheet collapse in a future world with rapidly rising atmospheric carbon dioxide (CO₂) concentrations.  Six sedimentary cores forming a north-to-south transect from the continental rise to the abyssal plain of the western Ross Sea were examined in order to identify potential sedimentary signatures of past marine-based ice sheet variability and associated oceanographic change. A lithofacies scheme and stratigraphic framework were developed, which allowed the identification of shifting sedimentary processes through time. The sediments are interpreted to have been deposited primarily under the influence of bottom currents, most likely from changing rates of dense Antarctic Bottom Water (AABW) formation over glacial-interglacial cycles. Two dominant lithofacies (laminated and bioturbated) are recognised in the Pleistocene contourite sequences. Laminated facies alongside reduced ice-rafted debris (IRD) fluxes and reduced biological productivity are interpreted to represent expanded ice sheet and sea ice margins during glacial conditions, which acted to restrict surface water ventilation resulting in less oxygenated bottom waters. Conversely, laminated facies alongside reduced IRD fluxes and increased productivity are inferred to represent a reduction of ice shelf and sea ice cover resulting in enhanced AABW formation and sediment delivery. In general, it is interpreted that bioturbated facies in combination with enhanced productivity are common during interglacial conditions, with peaks in IRD associated with ice sheet retreat events leading into interglacial conditions. However, the relationships between laminated and bioturbated facies vary between sites, and facies at most sites generally alternate on timescales exceeding that of individual glacial-interglacial cycles (<100 kyr). Nonetheless, there are clear baseline shifts in the facies distributions through time across the sites, and it is inferred these represent step-like shifts in the ice sheet volume and sea ice processes on the continental shelf and above the study sites during the Pleistocene.  This thesis also assesses and compares three independent methodologies of obtaining IRD mass accumulation rates (MARs). The three methodologies include counting clasts >2 mm in x-ray images, the sieved weight percentage of the medium-to-coarse sand fraction (250 µm-2 mm), and volumetric estimates of the > 125 µm sand fraction using a laser particle sizer. The x-ray and sieve methods produced comparable results, while the volumetric estimate, although showing comparable long-term trends, produces a lesser correlation to the other two methods.  Spectral analysis of the IRD content and the magnetic susceptibility data series reveals that during the Early Pleistocene (2.5-1.2 Ma) ice discharge into the western Ross Sea was paced by the 41 kyr and 100 kyr cycles of obliquity and eccentricity, respectively. The Mid-Pleistocene Transition (MPT;1.2-0.8 Ma) was characterised by a switch to a higher-frequency, lower-amplitude IRD flux during a long-term period of high power in eccentricity, obliquity and precession (˜23 kyr) observed in the orbital solutions, suggesting a relatively linear response to orbital forcing at this time. The colder climate state of the Late Pleistocene (0.8-0.01 Ma) is characterised by IRD fluctuations modulated primarily by the 100 kyr eccentricity forcing that became dominant by 400 ka. In the western Ross Sea, IRD fluxes show a clear response to the orbital pacing of glacial-interglacial cycles, but are equivocal in identifying the magnitude of ice sheet loss or growth through glacial-interglacial cycles.</p>

No abstract

<p>This thesis investigates glacimarine sedimentation processes operating on the continental margin of the western Ross Sea during the Pleistocene (˜2.5 Ma). This time period is characterised by a major global cooling step at ˜0.8 Ma, although several proposed episodes of major marine-based Antarctic Ice Sheet (AIS) retreat in warm interglacial periods are inferred to have occurred after this time. Constraining the timing and magnitude of past marine-based AIS retreat events in the Ross Sea through this time will improve our understanding of the forcing mechanisms and thresholds that drive marine-based ice sheet retreat. Identifying such mechanisms and thresholds is crucial for assisting predictive models of potential ice sheet collapse in a future world with rapidly rising atmospheric carbon dioxide (CO₂) concentrations.  Six sedimentary cores forming a north-to-south transect from the continental rise to the abyssal plain of the western Ross Sea were examined in order to identify potential sedimentary signatures of past marine-based ice sheet variability and associated oceanographic change. A lithofacies scheme and stratigraphic framework were developed, which allowed the identification of shifting sedimentary processes through time. The sediments are interpreted to have been deposited primarily under the influence of bottom currents, most likely from changing rates of dense Antarctic Bottom Water (AABW) formation over glacial-interglacial cycles. Two dominant lithofacies (laminated and bioturbated) are recognised in the Pleistocene contourite sequences. Laminated facies alongside reduced ice-rafted debris (IRD) fluxes and reduced biological productivity are interpreted to represent expanded ice sheet and sea ice margins during glacial conditions, which acted to restrict surface water ventilation resulting in less oxygenated bottom waters. Conversely, laminated facies alongside reduced IRD fluxes and increased productivity are inferred to represent a reduction of ice shelf and sea ice cover resulting in enhanced AABW formation and sediment delivery. In general, it is interpreted that bioturbated facies in combination with enhanced productivity are common during interglacial conditions, with peaks in IRD associated with ice sheet retreat events leading into interglacial conditions. However, the relationships between laminated and bioturbated facies vary between sites, and facies at most sites generally alternate on timescales exceeding that of individual glacial-interglacial cycles (<100 kyr). Nonetheless, there are clear baseline shifts in the facies distributions through time across the sites, and it is inferred these represent step-like shifts in the ice sheet volume and sea ice processes on the continental shelf and above the study sites during the Pleistocene.  This thesis also assesses and compares three independent methodologies of obtaining IRD mass accumulation rates (MARs). The three methodologies include counting clasts >2 mm in x-ray images, the sieved weight percentage of the medium-to-coarse sand fraction (250 µm-2 mm), and volumetric estimates of the > 125 µm sand fraction using a laser particle sizer. The x-ray and sieve methods produced comparable results, while the volumetric estimate, although showing comparable long-term trends, produces a lesser correlation to the other two methods.  Spectral analysis of the IRD content and the magnetic susceptibility data series reveals that during the Early Pleistocene (2.5-1.2 Ma) ice discharge into the western Ross Sea was paced by the 41 kyr and 100 kyr cycles of obliquity and eccentricity, respectively. The Mid-Pleistocene Transition (MPT;1.2-0.8 Ma) was characterised by a switch to a higher-frequency, lower-amplitude IRD flux during a long-term period of high power in eccentricity, obliquity and precession (˜23 kyr) observed in the orbital solutions, suggesting a relatively linear response to orbital forcing at this time. The colder climate state of the Late Pleistocene (0.8-0.01 Ma) is characterised by IRD fluctuations modulated primarily by the 100 kyr eccentricity forcing that became dominant by 400 ka. In the western Ross Sea, IRD fluxes show a clear response to the orbital pacing of glacial-interglacial cycles, but are equivocal in identifying the magnitude of ice sheet loss or growth through glacial-interglacial cycles.</p>