A study of altering the conductive properties of wool fibers by applying copper selenide is presented. The researched modification of wool fibers was based on a two-stage adsorption-diffusion process. X-ray diffraction, scanning electron microscope, energy-dispersive X-ray spectrum, and Fourier transform infrared spectroscopy were performed to evaluate the morphological and physical characteristics of all CuxSe-coated wool fibers. X-ray diffraction (XRD) data showed a single, Cu0.87Se (klockmannite), crystalline phase present, while Atomic Absorption Spectroscopy (AAS) and Energy Dispersive X-ray (EDX) analyses showed that the concentrations of Cu and Se in copper selenide coatings depend on the number of wool fiber treatment cycles. It was determined that a dense layer of CuxSe grows through a nucleation mechanism followed by particle growth to fill out the complete surface. It was found that the conductivity of the coated wool fibers depends on the quality and density of the copper selenide coating, thus the resistance of electrically impermeable wool fibers can be reduced to 100 Ω by increasing the number of treatment cycles.

Textile production has been steadily increasing for a few decades and, as a result, the amount of industrial textile waste is also increasing. This waste can be reused as raw material to produce new functional composites. Such materials can be used for special purposes with varying combinations of physical and chemical properties by using polymers modified with thin semiconductive or electrically conductive layers of binary inorganic compounds. In this paper, a study of the possibilities of altering the properties of synthetic fiber conductivity by modification with copper selenide is presented. A two-step adsorption/diffusion method was used for the copper selenide layer forming on the surface of the fibers. The treatment process was repeated cyclically. To evaluate the morphological properties of CuxSe treated fibers, scanning electron microscopy (SEM) and energy dispersion X-ray (EDX) were performed. The study showed that the chosen modification method is more suitable for PA and PAN fibers. Dense layers of copper selenides were successfully formed on their surface, which significantly reduced their electrical resistance.