Oil fields in Romania were active in the period 1900–2020, some of which will close due to declining oil production and especially due to reduced processing after the application of European Community recommendations to give up fossil fuels and the use of renewable fuel. The rehabilitation of the soil affected by hydrocarbon pollution is carried out with public funds. This is why, when transferring the land to the local community, an oil pollution assessment study is carried out. If the hydrocarbon content is less than 1000 mg/kg dry matter, the soil is not depolluted. In the Moinesti oil area, Romania, against the background of the increased incidence of breast cancers in women who worked in oil facilities, a study was conducted on the natural radioactivity of abandoned oil areas. The results of this analysis are presented and discussed in this article. It is the first study of radioactivity of the oil tank farm affected by oil pollution, its purpose being to draw attention in detecting radioactive elements when handing over land affected by oil pollution (but which respects the maximum levels of pollutant) to the local community.
The aim of this study was to improve the quality of a vegetable oil, having in view its use as a quenchant for metallic parts in aircrafts. A process of pyrolysis under vacuum was applied to obtain a bio-oil with reduced viscosity and good quenching properties. Preliminarily, the rapeseed oil was fast pyrolyzed at temperature in the range of 300–375 °C and absolute pressure of 1 μbar. Some results such as viscosity and yields of bio-oil were obtained with a narrowing of the temperature range between 300–320 °C, for further processing. Quenching tests with bio-oils on stainless steel 25CD4 showed cooling curves closer to those of the standard mineral oil (Castrol IloquenchTM 1), by comparing them with unprocessed vegetable oil. The hardness of the steel after treatment rose from 29–30 HRC to 43–45 HRC, in accordance with requirements (35–45 HRC). Therefore, the conclusion is that bio-oils obtained by pyrolysis under vacuum are good quenchant proceeds from this study.
The analysis of the corrosion phenomenon of the installations of the largest refinery in Romania confirmed the existence of its conditions, in the atmospheric distillation plants of crude oil, in the heat exchangers, and in the petrol and diesel hydrofining plants. However, the slightest effect of this phenomenon was found in the dome, the plates, and the exhaust pipes at the top of the distillation column, as well as in the reflux vessel of the atmospheric distillation plant. The main cause of the corrosion phenomenon and the increase in the corrosion areas of the material of the crude oil refining installations is the presence of hydrochloric acid, obtained after incorrect desalination (hydrolysis of calcium and magnesium chloride). To prevent this phenomenon, in laboratory conditions, we tested an antacid inhibitor (alkyl phenol) and a residual product (undistilled polyamine), with the role of supplementing the commercial inhibitor with a cheap product. The effectiveness of these additives was evaluated by introducing specimens made from the material taken from the refining column and from the reflux vessel into a solution of hydrochloric acid of various concentrations (5–15%). This solution was treated with the two corrosion inhibitors, the analysis of their effectiveness being performed at concentrations ranging between 0.05 and 0.2%. In addition, in this article, we deduced the equations of variation of the corrosion rate, depending on the working temperature of the refinery.
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